Formula of STR and Sommerfeld (SO)

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Kinetic Energy

K r e = m c 2 m 0 c 2 . (18)

K r e = p r e 2 m 0 + m . (23)

K r e , n = m e c 2 m n c 2 . (26)

K r e , n = p r e , n 2 m e + m n . (29)

Energy-Momentum Relationship

( m 0 c 2 ) 2 + p 2 c 2 = ( m c 2 ) . (17)

Holds in isolated systems in free space

( m e c 2 ) 2 p n 2 c 2 = ( m n c 2 ) 2 . (25)

Applicable to an electron in a hydrogen atom

Energy Levels of a Hydrogen Atom

E S O = K r e = m 0 c 2 m c 2 . (18)

E SO , n = m e c 2 [ 1 ( n 2 n 2 α 2 ) 1 / 2 ] , n = 1 , 2 , . *

E SO , n α 2 m e c 2 2 n 2 ( 1 + 3 α 2 4 n 2 + 5 8 α 4 n 4 ) . *

E re , n = K re , n = m n c 2 m e c 2 . (34)

E re , n = m e c 2 [ ( n 2 n 2 + α 2 ) 1 / 2 1 ] , n = 0 , 1 , 2 , . (40b)

E re , n α 2 m e c 2 2 n 2 ( 1 3 α 2 4 n 2 + 5 α 4 8 n 4 ) . (41c)

E 1

E SO , 1 = 13.60624 eV . *

E re , 1 = 13.60515 eV . *