(a)

Reaction Eq.

Eq. No.

Reaction rate constant k_i

Nominal Value of k_i

$O+O_2\to O_3$

(3)

k₁

1.63 × 10⁻¹⁶

$O_2\to 2O$

(4)

k₃

Changes depending on time t [1] [10] .

(b)

Reaction Eq.

Eq. No.

Reaction rate constant k_i

Nominal Value of k_i

$O+O_3\to 2O_2$

(5)

k₂

4.66 × 10⁻¹⁶

$O_3\to O+O_2$

(6)

k₄

Changes depending on time t [1] [10]

$2O_3\to 3O_2$

(7)

k₅

8.60 × 10⁻¹⁶

$Cl+O_3\to ClO+O_2$

(8)

k₆

6.09 × 10⁻³⁷

$ClO+O\to Cl+O_2$

(9)

k₇

2.41 × 10⁻¹⁹