Primary Analyst | C14:0 | C16:0 | C18:0 | C22:6 | C14:0 | C16:0 | C18:0 | C22:6 | C14:0 | C16:0 | C18:0 | C22:6 |
Approx. Spiked Conc (%) | 1.7 | 18 | 0.6 | 10 | 2.0 | 22.0 | 0.8 | 12 | 3.3 | 34 | 1.4 | 22 |
Replicate-1 | 96.0 | 96.0 | 86.6 | 117.1 | 95.4 | 90.6 | 96.6 | 106.6 | 92.8 | 86.0 | 88.7 | 106.2 |
Replicate-2 | 87.2 | 88.2 | 88.5 | 113.1 | 89.7 | 82.6 | 86.9 | 102.8 | 96.8 | 91.3 | 91.9 | 112.8 |
Replicate-3 | 92.7 | 100.3 | 95.1 | 113.0 | 100.8 | 96.7 | 99.7 | 117.4 | 100.5 | 94.3 | 93.2 | 113.6 |
Replicate-4 | 97.5 | 95.6 | 97.8 | 119.2 | 99.1 | 93.9 | 88.9 | 108.1 | 100.1 | 95.0 | 94.5 | 114.4 |
Replicate-5 | 89.1 | 82.3 | 80.7 | 111.8 | 93.9 | 89.9 | 91.0 | 115.5 | 96.8 | 91.5 | 91.8 | 111.3 |
Replicate-6 | 99.1 | 94.7 | 91.9 | 112.8 | 99.6 | 96.0 | 91.5 | 114.5 | 92.7 | 86.1 | 89.1 | 106.6 |
Replicate-7 | 94.2 | 93.3 | 100.3 | 117.1 | 87.3 | 83.2 | 94.1 | 108.1 | 91.8 | 86.6 | 83.1 | 103.9 |
Replicate-8 | 82.9 | 82.9 | 97.0 | 100.7 | 85.6 | 81.0 | 86.5 | 104.9 | 92.1 | 89.3 | 90.0 | 109.6 |
Replicate-9 | 93.5 | 90.0 | 96.5 | 113.8 | 82.0 | 80.9 | 87.6 | 104.2 | 90.8 | 87.1 | 88.0 | 105.1 |
Mean, primary analyst | 92.5 | 91.5 | 92.7 | 113.2 | 92.6 | 88.3 | 91.4 | 109.1 | 94.9 | 89.7 | 90.0 | 109.3 |
Std Deviation | 5.2 | 6.1 | 6.3 | 5.3 | 6.8 | 6.5 | 4.6 | 5.3 | 3.7 | 3.5 | 3.4 | 3.9 |
RSD (%) | 5.6 | 6.7 | 6.8 | 4.7 | 7.3 | 7.3 | 5.0 | 4.9 | 3.9 | 3.9 | 3.8 | 3.6 |
Secondary Analyst | C14:0 | C16:0 | C18:0 | C22:6 | C14:0 | C16:0 | C18:0 | C22:6 | C14:0 | C16:0 | C18:0 | C22:6 |
Spike-1 | 87.3 | 88.6 | 83.5 | 115.6 | 86.9 | 83.8 | 80.3 | 98.8 | 97.5 | 94.8 | 93.5 | 114.8 |
Spike-2 | 86.3 | 80.9 | 81.3 | 112.3 | 87.8 | 81.4 | 81.0 | 101.1 | 92.7 | 88.4 | 86.4 | 106.3 |
Spike-3 | 89.4 | 88.4 | 94.9 | 111.9 | 88.9 | 85.6 | 80.3 | 106.2 | 97.2 | 93.0 | 94.7 | 113.4 |
Mean, secondary analyst | 87.7 | 86.0 | 86.6 | 113.3 | 87.9 | 83.6 | 80.5 | 102.0 | 95.8 | 92.1 | 91.5 | 111.5 |
RE (%) to Primary Analyst | −5.2 | −6.0 | −6.6 | 0.1 | −5.1 | −5.3 | −11.9 | −6.5 | 0.9 | 2.7 | 1.7 | 2.0 |