a | Ratio of the packing surface area to the reactor volume (m−1) |
A(g) | Feed compound |
CA | Concentration of species A (mol/m3) |
Ci | Concentration of species i (mol/m3) |
Ci,in | Initial concentration of species i |
Ci,o | Inlet concentration of species i (mol/m3) |
Ci,out | Concentration of species i at the outlet (mol/m3) |
CR | Concentration of species R (mol/m3) |
CS | Concentration of species S (mol/m3) |
CP | Surface concentration of deactivated sites (mol/m2) |
d | Reactor diameter (m) |
DA | Dispersion coefficient for compound A (m2/s) |
Di | Dispersion coefficient for compound i (m2/s) |
DR | Dispersion coefficient for compound R (m2/s) |
DS | Dispersion coefficient for compound S (m2/s) |
i | Species A, R, S, or P. |
k1 | Reaction rate coefficient of the first forward reaction (m2·s−1·mol−1) |
k1r | Reaction rate coefficient of the first reverse reaction (m2·s−1·mol−1) |
k2 | Reaction rate coefficient of the second forward reaction (s−1) |
k2r | Reaction rate coefficient of the second reverse reaction (s−1) |
k3 | Reaction rate coefficient of the third forward reaction (m2·s−1·mol−1) |
k3r | Reaction rate coefficient of the third reverse reaction (s−1) |
L | Reactor length (m) |
m | Parameter in catalyst distribution equation |
P(s) | Undesirable deactivating end product |
R(g) | Desirable product |
S(g) | Undesirable product |
t | Time (s) |
υ | Fluid velocity (m/s) |
x | Location along the packed bed (m) |
Z | Surface concentration of catalytic sites (mol/m2) |
Z0 | Value of Z for uniform catalyst distribution (mol/m2) |