a

Ratio of the packing surface area to the reactor volume (m−1)

A(g)

Feed compound

CA

Concentration of species A (mol/m3)

Ci

Concentration of species i (mol/m3)

Ci,in

Initial concentration of species i

Ci,o

Inlet concentration of species i (mol/m3)

Ci,out

Concentration of species i at the outlet (mol/m3)

CR

Concentration of species R (mol/m3)

CS

Concentration of species S (mol/m3)

CP

Surface concentration of deactivated sites (mol/m2)

d

Reactor diameter (m)

DA

Dispersion coefficient for compound A (m2/s)

Di

Dispersion coefficient for compound i (m2/s)

DR

Dispersion coefficient for compound R (m2/s)

DS

Dispersion coefficient for compound S (m2/s)

i

Species A, R, S, or P.

k1

Reaction rate coefficient of the first forward reaction (m2·s−1·mol−1)

k1r

Reaction rate coefficient of the first reverse reaction (m2·s−1·mol−1)

k2

Reaction rate coefficient of the second forward reaction (s−1)

k2r

Reaction rate coefficient of the second reverse reaction (s−1)

k3

Reaction rate coefficient of the third forward reaction (m2·s−1·mol−1)

k3r

Reaction rate coefficient of the third reverse reaction (s−1)

L

Reactor length (m)

m

Parameter in catalyst distribution equation

P(s)

Undesirable deactivating end product

R(g)

Desirable product

S(g)

Undesirable product

t

Time (s)

υ

Fluid velocity (m/s)

x

Location along the packed bed (m)

Z

Surface concentration of catalytic sites (mol/m2)

Z0

Value of Z for uniform catalyst distribution (mol/m2)