Sample | LL8 | LJ6 | LK6 | LM10 | LF14 | Km21 | Km35 | Km49 | LL7 | Km33 | Km41 | Km30 | Km44 | Km57 | LK10 | Km59 | Km28 | Km20 | Km18 | Km11 | Km68 | Km74 |
Si2O | 50.59 | 51.06 | 51.35 | 52.09 | 53.15 | 55.46 | 55.96 | 56.1 | 56.11 | 56.34 | 57.28 | 57.63 | 59.1 | 60.45 | 61.56 | 60.84 | 61.23 | 61.87 | 63.31 | 63.42 | 63.64 | 64.1 |
TiO2 | 0.76 | 0.88 | 0.72 | 0.73 | 0.77 | 0.47 | 0.49 | 0.64 | 0.68 | 0.63 | 0.68 | 0.53 | 0.69 | 0.6 | 0.57 | 0.57 | 0.61 | 0.31 | 0.38 | 0.33 | 0.39 | 0.36 |
Al2O3 | 13.22 | 12.19 | 11.26 | 13. 09 | 12.16 | 17.16 | 14.87 | 18.47 | 11.38 | 14.52 | 18.68 | 12.73 | 11.57 | 12.93 | 14.93 | 14.93 | 16.56 | 16.11 | 16.17 | 15.64 | 17.42 | 15.65 |
Fe2O3 | 10 | 8.26 | 8.71 | 8.05 | 8.04 | 4.97 | 7.9 | 5.34 | 7.71 | 7.63 | 5.19 | 6.03 | 5.17 | 6.58 | 5.51 | 5.51 | 4.39 | 5.5 | 5.44 | 5.48 | 5.36 | 4.89 |
MnO | 0.18 | 0.14 | 0.2 | 0.18 | 0.15 | 0.09 | 0.17 | 0.09 | 0.16 | 0.16 | 0.16 | 0.15 | 0.12 | 0.15 | 0.12 | 0.12 | 0.15 | 0.08 | 0.23 | 0.18 | 0.13 | 0.16 |
MgO | 8.13 | 10.29 | 9.47 | 6.54 | 7.47 | 2.52 | 5.86 | 3.34 | 6. 48 | 5.96 | 4.31 | 7.21 | 9.25 | 4.73 | 4.19 | 4.19 | 4.76 | 3.12 | 2.23 | 3.27 | 3.16 | 2.74 |
CaO | 9.38 | 9. 33 | 9.07 | 9.2 | 9.88 | 4.21 | 6.8 | 2.87 | 7.82 | 4.87 | 2.74 | 8.31 | 7.04 | 5.18 | 5.97 | 5.97 | 4.62 | 4.85 | 2.5 | 4.84 | 3.14 | 4.31 |
Na2O | 2.99 | 2.08 | 1.98 | 2.16 | 2.58 | 3.46 | 2.36 | 3.54 | 2.86 | 3.18 | 3.35 | 2.38 | 2.15 | 3.4 | 3.43 | 3.43 | 2.76 | 3.26 | 3.97 | 3.12 | 3.21 | 3.32 |
K2O | 3.02 | 3.73 | 4.81 | 5.07 | 3.92 | 6.82 | 3.01 | 6.65 | 3.46 | 3.46 | 5.86 | 3.17 | 3.37 | 3.67 | 2.16 | 2.16 | 3.11 | 2.63 | 2.49 | 2.44 | 2.71 | 2.63 |
P2O5 | 0.41 | 0.59 | 0.78 | 0.69 | 0.41 | 0.62 | 0.23 | 0.68 | 0.51 | 0.58 | 0.54 | 0.37 | 0.42 | 0.49 | 0.3 | 0.3 | 0.39 | 0.038 | 0.23 | 0.14 | 0.1 | 0.13 |
L.O.I | 1.32 | 1. 17 | 1.32 | 1.94 | 1.47 | 3.96 | 2.27 | 2.21 | 2.56 | 2.56 | 1.08 | 1.16 | 0.98 | 1.56 | 0.99 | 1.83 | 2.03 | 1.74 | 2.78 | 1.1 | 0.89 | 1.64 |
Total | 100 | 99.72 | 99.67 | 99.74 | 100 | 99.74 | 99.92 | 99.93 | 99.73 | 99.89 | 99.87 | 99.67 | 99.86 | 99.74 | 99.73 | 99.85 | 100.6 | 99.85 | 99.73 | 99.96 | 99.97 | 99.93 |
V | 94.8 | 100.2 | 101.9 | 99.46 | 99.35 | 137.4 | 127.1 | 139.5 | 96.5 | 129.3 | 89.4 | 96.5 | 94.6 | 96.8 | 99.1 | 99.6 | 110.3 | 142.5 | 129.4 | 136.8 | 120.2 | 110.7 |
Cr | 134 | 348 | 517 | 128 | 479 | 180 | 125 | 129 | 122 | 213 | 198 | 134 | 128 | 145 | 180 | 106 | 117 | 159 | 151 | 150 | 143 | 118 |
Ni | 52.6 | 61.5 | 55.7 | 52.9 | 54.3 | 57.3 | 52.4 | 77.6 | 53.7 | 60 | 55 | 77.6 | 69.8 | 59.4 | 51.8 | 59.3 | 78.1 | 90.2 | 98.6 | 101.4 | 71.3 | 91.5 |
Co | 34.6 | 39.2 | 38.9 | 33.3 | 37.4 | 11.4 | 12.1 | 14.2 | 26.3 | 11.5 | 12.6 | 12.7 | 12.1 | 13 | 19.3 | 12.3 | 11.5 | 11.9 | 13 | 12.2 | 13.8 | 14.5 |
Zn | 76.3 | 55.9 | 149 | 101.2 | 58.9 | 56.4 | 74.4 | 55.2 | 101.7 | 51.4 | 63.3 | 57 | 57.5 | 54.4 | 87.6 | 55.8 | 55.4 | 52.1 | 53.8 | 50.5 | 58.3 | 64.3 |
Ga | 16.5 | 14.3 | 14.1 | 15 | 15.9 | 15 | 16.3 | 14.2 | 14.2 | 15.4 | 14.3 | 17.8 | 14.4 | 18.1 | 22.2 | 21.3 | 17.4 | 18.1 | 19 | 19.6 | 18.2 | 17.8 |
Sn | 2 | 2.3 | 1.8 | 2.2 | 2.2 | 3 | 3 | 1.9 | 1.9 | 1.9 | 2.2 | 2 | 1.8 | 1.9 | 2.4 | 1.8 | 1.7 | 2 | 2.9 | 1.8 | 2 | 2.4 |
W | 3.3 | 4.8 | 6.1 | 4.6 | 12.5 | 1.5 | 1.2 | 1.2 | 3.1 | 1.3 | 1.4 | 1.3 | 1.2 | 1.1 | 7.9 | 1 | 1 | 1.8 | 1.1 | 1.2 | 1.4 | 0.9 |
Ba | 1250 | 1212 | 1558 | 1623 | 1222 | 337.4 | 315.7 | 426.6 | 1415 | 348.6 | 346.7 | 354.3 | 341 | 320.5 | 1224 | 304.1 | 342.6 | 525.2 | 362.4 | 336 | 396.8 | 278.3 |
Sr | 745 | 817 | 791 | 955 | 631 | 301.9 | 270.5 | 281.2 | 710 | 305.5 | 335 | 273.8 | 301.6 | 337.1 | 1237 | 276.6 | 292.1 | 348.9 | 404.9 | 446.7 | 333.4 | 215.7 |
Rb | 79.7 | 131.8 | 125.4 | 118.5 | 96.7 | 74.3 | 76.8 | 99.1 | 75.5 | 82.4 | 117.3 | 125.7 | 99.3 | 128.5 | 78.9 | 115.7 | 148.6 | 132.1 | 128.9 | 152.4 | 135.3 | 158.2 |
Nb | 5.7 | 12 | 7.4 | 10.2 | 10.1 | 10.5 | 15.7 | 10.2 | 8.6 | 14.5 | 10.7 | 11.6 | 11.4 | 11.1 | 10.6 | 11.5 | 11.6 | 12.3 | 11.1 | 11.9 | 10.9 | 12.2 |
Y | 19.6 | 18.9 | 20.6 | 19.5 | 20.3 | 11.3 | 15.2 | 11.1 | 16.9 | 12.4 | 13.9 | 11.3 | 12.6 | 11.8 | 14.1 | 12.6 | 12.6 | 12.2 | 13.5 | 12.2 | 11.5 | 14.7 |
Zr | 87.8 | 41.9 | 55.3 | 66.8 | 24.5 | 70.3 | 89.6 | 85.4 | 73.2 | 70.6 | 88.7 | 81.1 | 88.7 | 105 | 20.9 | 91.4 | 106.1 | 99.5 | 120 | 138.3 | 143.9 | 136.5 |
Cs | 1.5 | 8.2 | 5.6 | 1.3 | 3.8 | 3.4 | 2.7 | 3.1 | 1 | 3.9 | 2.6 | 1.3 | 1.5 | 2.2 | 4.9 | 1.8 | 4.6 | 5.7 | 10.6 | 6.2 | 7.1 | 8.4 |
Hf | 2.8 | 1.8 | 2.1 | 2.4 | 1.2 | 1.9 | 2.4 | 2.8 | 2.6 | 1.8 | 2.1 | 2.4 | 2.5 | 2.2 | 1 | 3.4 | 4.1 | 5.7 | 5.1 | 4.6 | 4.3 | 5.2 |
Ta | 0.5 | 1.4 | 0.7 | 0.9 | 1.4 | 1.3 | 0.9 | 0.5 | 0.8 | 1.1 | 1.4 | 0.8 | 0.5 | 0.9 | 1.3 | 1.7 | 1.2 | 1.1 | 0.9 | 1.2 | 1.1 | 0.9 |
Th | 3.9 | 3.6 | 5.8 | 6.1 | 3.7 | 11.4 | 12.2 | 10.6 | 5.3 | 11.4 | 10.9 | 11.9 | 11.8 | 11.4 | 4.7 | 11.3 | 12.7 | 11.9 | 13.1 | 12.1 | 11.8 | 10.2 |
U | 1.3 | 1.7 | 2.1 | 2 | 1.3 | 1.7 | 2.6 | 2.1 | 1.8 | 2.5 | 2.4 | 2.8 | 2.4 | 2.4 | 1.7 | 2.7 | 3.3 | 3.3 | 3.2 | 2.8 | 2.4 | 2.7 |
La | 17.1 | 23.3 | 23.4 | 26.3 | 17.7 | 20.6 | 23.1 | 16.2 | 20.9 | 23.2 | 17.7 | 21.4 | 25.5 | 20.1 | 21.3 | 21.3 | 15.6 | 32.8 | 19.6 | 26.7 | 25.8 | 34.2 |
Ce | 33.5 | 45 | 46.1 | 50.1 | 35.3 | 59.3 | 44.6 | 62.4 | 39.5 | 41.4 | 39.8 | 55.2 | 57.4 | 41.8 | 40.6 | 76.4 | 56.8 | 69.9 | 46.4 | 47.9 | 49.6 | 41.9 |
Pr | 4.4 | 6 | 6.2 | 6.5 | 4.8 | 5.1 | 4.9 | 5 | 5 | 5.4 | 4.8 | 5.9 | 6.1 | 4.4 | 5.1 | 6.5 | 5.8 | 8.1 | 7.2 | 4.5 | 6.4 | 6.7 |
Nd | 18 | 22.7 | 23.9 | 27.3 | 18.6 | 18.6 | 21.1 | 22.3 | 20.4 | 19.3 | 21.9 | 23.4 | 17.8 | 25.3 | 19.2 | 21.2 | 34.1 | 31.2 | 27.3 | 16.4 | 25.1 | 24.2 |
Sm | 4.9 | 5.5 | 6.4 | 6.8 | 5.1 | 4.7 | 5.1 | 5.6 | 5.1 | 6.2 | 5.3 | 5.5 | 6.4 | 4.8 | 4.6 | 6.8 | 3.7 | 6.7 | 5.1 | 4.3 | 5.2 | 4.7 |
Eu | 1.9 | 1.8 | 2.1 | 2.5 | 1.7 | 1.7 | 1.4 | 1.8 | 1.9 | 1.7 | 1.6 | 1.9 | 1.1 | 1.1 | 1.8 | 0.9 | 1 | 1.1 | 1.2 | 1 | 1.1 | 1.1 |
Gd | 3.7 | 4.9 | 5.2 | 5 | 4.4 | 3.4 | 3.6 | 4.1 | 3.7 | 4.2 | 4.8 | 5.1 | 3.7 | 4.9 | 3.5 | 3.4 | 6.1 | 5.8 | 5.2 | 3.9 | 5.1 | 5.7 |
Tb | 0.7 | 0.8 | 0.8 | 0.9 | 0.7 | 0.7 | 0.6 | 0.7 | 0.7 | 0.8 | 0.8 | 0.7 | 0.9 | 0.6 | 0.6 | 0.9 | 0.8 | 0.7 | 0.9 | 0.7 | 0.9 | 0.9 |
Dy | 4 | 4.2 | 4.5 | 4.2 | 4.3 | 2.9 | 3.5 | 3.7 | 3.5 | 3.4 | 4.2 | 4.1 | 4.2 | 3.6 | 2.9 | 4.3 | 4.5 | 4.6 | 4.1 | 3.6 | 5.2 | 3.7 |
Ho | 0.9 | 0.8 | 0.9 | 0.9 | 0.9 | 0.6 | 0.6 | 0.5 | 0.7 | 0.8 | 0.8 | 0.9 | 0.7 | 0.9 | 0.6 | 0.9 | 0.8 | 0.9 | 0.9 | 0.7 | 0.9 | 0.9 |
Er | 2.1 | 2 | 2.1 | 2.1 | 2.1 | 1.4 | 1.8 | 1.7 | 1.8 | 2.1 | 1.9 | 2.1 | 2.2 | 2.1 | 1.4 | 1.4 | 2.9 | 2.8 | 2.5 | 2.3 | 3.1 | 3.4 |
Tm | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.5 | 0.3 | 0.5 | 0.4 | 0.4 | 0.4 | 0.5 | 0.3 | 0.5 | 0.4 | 0.4 | 0.3 | 0.3 | 0.5 | 0.4 |
Yb | 2.5 | 2.2 | 2.3 | 2.3 | 2.5 | 1.5 | 1.9 | 2 | 1.9 | 2.3 | 2.2 | 2.1 | 2.5 | 2.3 | 1.5 | 2.1 | 3.4 | 2.6 | 2.5 | 2.2 | 2.1 | 3.4 |
Lu | 0.5 | 0.4 | 0.5 | 0.5 | 0.5 | 0.3 | 0.5 | 0.5 | 0.5 | 0.5 | 0.4 | 0.5 | 0.5 | 0.4 | 0.3 | 0.5 | 0.4 | 0.4 | 0.5 | 0.3 | 0.5 | 0.5 |