Position

δH (nH, mult; J in Hz)

δC

(mult)

HMBC

Long chain base

NH

8.61 (1H, d, J = 9.1)

-

-

1a, 1b

4.54 (1H, m)

62.4

(CH2)

2; 3

4.45 (1H, m)

2

5.14 (1H, m)

53.2

(CH)

1'; 1; 3

3

4.39 (1H, m)

77.2

(CH)

1; 2; 4; 5

4

4.32 (1H, m)

73.3

(CH)

5

5

2.00 (2H, m)

34.2

(CH2)

-

6 - 14

1.52 - 1.20 (18H, brs)

32.5 - 27.0

(CH2)9

-

15

2.19 (2H, m)

33.7

(CH2)

16

16

5.57 (1H, m)

131.2

(CH)

15

17

5.51 (1H, m)

131.1

(CH)

18

18

2.02 (2H, m)

33.6

(CH2)

17

19 - 24

1.52 - 1.20 (10H, brs)

32.5 - 27.0

(CH2)5

25

1.26 (1H, m)

23.3

(CH2)

-

26

0.88 (3H, t, J = 7.0)

14.6

(CH3)

25

N-acyl moiety

1'

-

175.5

(C)

-

2'

4.65 (2H, dt, J = 7.7, 3.7)

72.8

(CH2)

3'

2.26 (1H, m)

36.1

(CH2)

-

2.06 (1H, m)

2'

4' - 14'

1.52 - 1.20 (22H, brs)

32.5 - 27.0

(CH2)11

-

15'

1.26 (1H, m)

23.3

(CH2)

-

16'

0.88 (3H, t, J = 7.0)

14.6

(CH3)

15'