Samples | Al(III) added (µg L−1) | Proposed methodology | ETAAS | RE%b | ||
Al(III) found ± SD (µg L−1) | Recovery (%, n = 3) | Real Al(III) contents (µg L−1)a | Al(III) found ± SD (µg L−1) | |||
1 | - | 9.88 ± 1.47 | - | - | - | |
24.95 | 31.88 ± 1.42 | 70.14 | 7.41 | |||
49.91 | 61.26 ± 1.49 | 114.87 | ||||
2 | - | 30.00 ± 1.54 | - | 33.4 ± 0.02 | 10.17 | |
24.95 | 60.66 ± 1.53 | 119.03 | 22.5 | |||
49.91 | 77.05 ± 0.97 | 90.47 | ||||
3 | - | 62.90 ± 1.74 | - | - | - | |
24.95 | 92.96 ± 0.70 | 108.12 | 47.18 | |||
49.91 | 113.23 ± 1.27 | 100.66 | ||||
4 | - | 87.42 ± 1.98 | - | - | - | |
24.95 | 111.82 ± 1.86 | 99.37 | 65.56 | |||
49.91 | 137.59 ± 2.22 | 99.99 | ||||
5 | - | 93.21 ± 1.81 | - | 98.8 ± 0.08 | 5.65 | |
24.95 | 113.91 ± 1.47 | 95.44 | 69.91 | |||
49.91 | 145.24 ± 2.14 | 102.27 | ||||
6 | - | 130.69 ± 2.20 | - | - | - | |
24.95 | 156.38 ± 2.88 | 100.56 | 98.02 | |||
49.91 | 180.22 ± 2.87 | 99.7 | ||||
7 | - | 160.73 ± 1.11 | - | 163.7 ± 0.02 | 1.81 | |
24.95 | 186.28 ± 1.37 | 100.37 | 120.55 | |||
49.91 | 210.34 ± 2.67 | 99.81 |