Molecules

States

λ (nm)

eV

f

exp

fac-cis

13

314.98

3.9363

0.0162

290

(LMCT)

16

287.49

4.3127

0.0260

19

257.63

4.8124

0.0087

26

238.53

5.1979

0.0093

mer-cis

14

319.96

3.8750

0.0101

16

304.82

4.0675

0.0161

230

(π-π*)

19

263.97

4.6969

0.0292

22

251.81

4.9236

0.0079

mer-trans

14

321.58

3.8555

0.0119

19

283.60

4.3718

0.0170

22

257.28

4.8190

0.0223

27

244.79

5.0648

0.0337