trans-[Ru(NH3)4(isn)(bpa)]+2 | ||||||||||
Acetone | 50 | 1.80 | 1.72 | 0.566 | 0.491 | 0.477 | 0.540 | 1.04 | 0.075 | 0.528 |
100 | 2.49 | 2.36 | 0.569 | 0.493 | 0.469 | 0.552 | 1.06 | 0.076 | 0.531 | |
200 | 3.58 | 3.14 | 0.566 | 0.493 | 0.464 | 0.567 | 1.14 | 0.073 | 0.529 | |
300 | 4.24 | 3.80 | 0.569 | 0.493 | 0.454 | 0.576 | 1.12 | 0.076 | 0.531 | |
Acetonitrile | 50 | 2.11 | 1.49 | 0.608 | 0.527 | 0.504 | 0.565 | 1.42 | 0.081 | 0.568 |
100 | 2.57 | 2.04 | 0.605 | 0.525 | 0.477 | 0.583 | 1.26 | 0.080 | 0.565 | |
200 | 3.70 | 2.82 | 0.605 | 0.525 | 0.465 | 0.597 | 1.31 | 0.080 | 0.565 | |
300 | 4.69 | 3.73 | 0.610 | 0.522 | 0.451 | 0.601 | 1.26 | 0.088 | 0.566 | |
Dimethyl sulfoxide | 50 | 0.63 | 0.77 | 0.342 | 0.276 | 0.250 | 0.357 | 0.81 | 0.066 | 0.309 |
100 | 0.93 | 1.23 | 0.342 | 0.271 | 0.248 | 0.364 | 0.76 | 0.071 | 0.306 | |
200 | 1.19 | 1.89 | 0.344 | 0.266 | 0.233 | 0.379 | 0.63 | 0.078 | 0.305 | |
300 | 1.05 | 2.43 | 0.347 | 0.264 | 0.163 | 0.401 | 0.43 | 0.083 | 0.305 | |
trans-[Ru(NH3)4(py)(bpa)]+2 | ||||||||||
Acetone | 50 | 3.09 | 3.04 | 0.515 | 0.447 | 0.456 | 0.483 | 1.02 | 0.068 | 0.481 |
100 | 4.42 | 4.46 | 0.515 | 0.447 | 0.457 | 0.489 | 0.99 | 0.068 | 0.481 | |
200 | 6.27 | 6.18 | 0.515 | 0.449 | 0.458 | 0.495 | 1.01 | 0.066 | 0.482 | |
300 | 7.69 | 7.71 | 0.513 | 0.452 | 0.463 | 0.493 | 1.00 | 0.061 | 0.483 | |
Acetonitrile | 50 | 3.53 | 3.27 | 0.549 | 0.479 | 0.483 | 0.515 | 1.08 | 0.070 | 0.514 |
100 | 5.06 | 4.88 | 0.552 | 0.479 | 0.483 | 0.520 | 1.04 | 0.073 | 0.516 | |
200 | 6.85 | 6.83 | 0.554 | 0.483 | 0.478 | 0.527 | 1.00 | 0.071 | 0.518 | |
300 | 8.59 | 8.63 | 0.554 | 0.479 | 0.478 | 0.530 | 1.00 | 0.075 | 0.516 | |
Dimethyl sulfoxide | 50 | 0.70 | 0.86 | 0.298 | 0.225 | 0.221 | 0.311 | 0.82 | 0.073 | 0.262 |
100 | 1.09 | 1.33 | 0.298 | 0.227 | 0.221 | 0.316 | 0.82 | 0.071 | 0.263 | |
200 | 1.63 | 2.09 | 0.300 | 0.227 | 0.222 | 0.325 | 0.78 | 0.073 | 0.264 | |
300 | 2.11 | 3.00 | 0.303 | 0.225 | 0.222 | 0.323 | 0.70 | 0.078 | 0.264 |