Sample “in natura”

Sample after sun exposure

Organic group

Vibration mode

Wave number cm−1

Band area

cm2

Wave number cm−1

Band area

cm2

-

-

2951, 2920, 2852

2426.27

2951, 2920, 2852

2319.07

-C-H (CH3),

-C-H (CH2)

Asymmetric and symmetrical axial deformation

1747

85.42

1747

83.11

-C=O

Axial deformation

1670

3.11

Absent

-

C=C (trans)

Axial deformation

1652

10.35

Absent

-

C=C (cis)

Axial deformation

1456

340.99

1460

388.63

-C-H (CH2)

Symmetrical angular deformation

1417

2.48

Absent

-

=C-H (cis)

Angular deformation

1396

1.89

Absent

-

=C-H (cis)

Angular deformation

1375

110.29

1375

134.35

-C-H (CH3)

Symmetrical angular deformation

1230

6.55

1238

5.36

C-O

Axial deformation

1217

0.85

Absent

-

C-O

Axial deformation

1163

79.60

1159

72.47

C-O

Axial deformation

721

72.45

721

68.78

-(CH2)n-

Asymmetric angular deformation