Entry | L | Subs. | Activator | Activity | Products (wt%) | α12 | Sα (%) | Bb (mol%) | |
C4-C20 | Solid | ||||||||
7 | 1 | 2-CH3 | TEA | 366 | 1.8 | 92.3 | 0.83 | 76.4 | n.d. |
8 | 1 | 2-CH3 | TIBA | 482 | 3.8 | 93.3 | 0.82 | 64.0 | n.d. |
9 | 2 | 2-F | TEA | 294 | 37.5 | 49.4 | 0.64 | 88.4 | 1 |
10 | 2 | 2-F | TIBA | 433 | 41.6 | 42.9 | 0.61 | 88.8 | 1 |
11 | 3 | 2-Br | TEA | 363 | 1.4 | 97.2 | 0.76 | 64.1 | n.d. |
12 | 3 | 2-Br | TIBA | 376 | 2.4 | 99.5 | 0.76 | 80.6 | n.d. |
13 | 4 | 4-CH3 | TEA | 212 | 25.6 | 53.1 | 0.75 | 86.2 | 4 |
14 | 4 | 4-CH3 | TIBA | 334 | 27.6 | 54.0 | 0.71 | 87.8 | 4 |
4 | 5 | 4-F | TEA | 326 | 19.9 | 61.3 | 0.73 | 81.3 | 4 |
5 | 5 | 4-F | TIBA | 549 | 20.5 | 65.7 | 0.66 | 82.5 | 3 |
15 | 6 | 4-Br | TEA | 260 | 25.8 | 52.6 | 0.70 | 84.9 | 2 |
16 | 6 | 4-Br | TIBA | 424 | 24.1 | 63.7 | 0.73 | 92.3 | 6 |
17 | 7 | 2,4-F2 | TEA | trace | - | - | - | - | - |
18 | 7 | 2,4-F2 | TIBA | trace | - | - | - | - | - |
19 | 8 | 2,4-Br2 | TEA | trace | - | - | - | - | - |
20 | 8 | 2,4-Br2 | TIBA | trace | - | - | - | - | - |
21 | 9 | 2,6-F2 | TEA | trace | - | - | - | - | - |
22 | 9 | 2,6-F2 | TIBA | trace | - | - | - | - | - |
Ref. [35] c | 2,6-(CH3)2 | TEA | 170 | 0 | 100 | - | n.d. | - | |
Ref. [32] d | None | TEA | 96 | 12.6 | 71.7 | n.d. | 92.5 | n.d. |