Analysis

Technique

Precipitate

m/z

Products

CHX 2% (Sigma)

Without polyethylene glycol

Fast atom bombardment

(FAB)

____________

505

Chlorhexidine

(not shown)

CHX 2% (Consepsis) with polyethylene glycol

Electron impact

_____________

89, 133, 177, 219, 459, 50, 547

CHX was not observed due to the high polyethylene glycol

content (not shown)

CHX 2% (Consepsis) with polyethylene glycol

FAB

______________

505

CHX

(Figure 1)

Polyethylene glycol

(Fluka)

Electron impact

_______________

89, 133, 177, 219, 459, 503, 547

Polyethylene glycol

spectra

(not shown)

NaOCl + CHX (Sigma) without polyethylene glycol

Time “0”

FAB

Brown

127

153

p-chloroaniline

p-chlorophenyl isocyanate

(Figure 3(a))

NaOCl + CHX

(Consepsis) with polyethylene glycol

24 h

Electron impact

Brown

153

Complex spectrum due to the large amount of polyethylene glycol

p-chlorophenyl isocyanate (not shown)

10 days

Electron impact

Brown

127

153

p-chloroaniline

p-chlorophenyl isocyanate (not shown)

20 days

Electron impact

Brown

127

153

p-chloroaniline

p-chlorophenyl isocyanate (not shown)

60 days

Linked scans

Brown

127

153

p-chloroaniline

p-chlorophenyl isocyanate (not shown)

90 days

Electron impact

Brown

127

153

p-chloroaniline

p-chlorophenyl isocyanate (not shown)

150 days

Electron impact

Brown

127

153

p-chloroaniline

p-chlorophenyl isocyanate (not shown)

180 days

Electron

impact

Brown

127

153

(almost disappeared)

p-chloroaniline

(Figure 3(b))