Analysis | Technique | Precipitate | m/z | Products |
CHX 2% (Sigma) Without polyethylene glycol | Fast atom bombardment (FAB) | ____________ | 505 | Chlorhexidine (not shown) |
CHX 2% (Consepsis) with polyethylene glycol | Electron impact | _____________ | 89, 133, 177, 219, 459, 50, 547 | CHX was not observed due to the high polyethylene glycol content (not shown) |
CHX 2% (Consepsis) with polyethylene glycol | FAB | ______________ | 505 | CHX (Figure 1) |
Polyethylene glycol (Fluka) | Electron impact | _______________ | 89, 133, 177, 219, 459, 503, 547 | Polyethylene glycol spectra (not shown) |
NaOCl + CHX (Sigma) without polyethylene glycol Time “0” | FAB | Brown
| 153 | p-chloroaniline p-chlorophenyl isocyanate (Figure 3(a)) |
NaOCl + CHX (Consepsis) with polyethylene glycol 24 h | Electron impact | Brown
| 153 | Complex spectrum due to the large amount of polyethylene glycol p-chlorophenyl isocyanate (not shown) |
10 days | Electron impact | Brown | | p-chloroaniline p-chlorophenyl isocyanate (not shown) |
20 days | Electron impact | Brown | | p-chloroaniline p-chlorophenyl isocyanate (not shown) |
60 days | Linked scans | Brown | | p-chloroaniline p-chlorophenyl isocyanate (not shown) |
90 days | Electron impact | Brown | | p-chloroaniline p-chlorophenyl isocyanate (not shown) |
150 days | Electron impact | Brown | | p-chloroaniline p-chlorophenyl isocyanate (not shown) |
180 days | Electron impact | Brown | (almost disappeared) | p-chloroaniline (Figure 3(b)) |