Compounds | uO-H | uC=O ring | uC=O carbox. | uN=C imine | uCOO− asy. | uCOO− sy. | u asy. | u sy. | uC=C arom. | uC-H arom. | uC-C aliph. | uC-H aliph. | uM-N | uM-O |
(HL) | 3421 | 1645 | 1724 | 1608 | 1419 | 1369 | - | - | 1586 | 2939 | 1197 | 2900 | - | - |
[Mn(HL)2(N3)2(H2O)2]∙H2O | 3390 | 1647 | Overlap | 1593 | 1417 | 1369 | 2123 2058 | 1311 | 1570 | 3064 | 1190 | 2927 | 543 | 505 |
[Co(HL)2(N3)2]∙H2O | 3442 | 1616 | Overlap | 1591 | 1421 | 1371 | 2123 2102 | 1311 | 1573 | Overlap | 1197 | 2935 | 505 | 445 |
[Ni(HL)2(N3)2]∙3H2O | 3390 | 1624 | 1735 | 1593 | 1417 | 1363 | 2121 2036 | 1311 | 1575 | Overlap | 1168 | Overlap | 545 | 475 |
[Zn(HL)2(N3)2]∙3H2O | 3464 | 1614 | 1735 | 1591 | 1417 | 1373 | 2065 | 1317 | 1560 | 3066 | 1141 | 2933 | 542 | 445 |
[Cd(HL)2(N3)2]∙2H2O | 3446 | 1616 | Overlap | 1591 | 1419 | 1375 | 2065 | 1317 | 1558 | 3064 | 1188 | 2930 | 505 | 460 |
[Hg(HL)2(N3)2]∙3H2O | 3346 | 1635 | Overlap | 1591 | 1417 | 1369 | 2125 2036 | 1313 | 1558 | 3064 | 1188 | 2900 | 505 | 453 |