As | 5.7 | 13 | 22.7 | 14 | 4 | 1050 | 169 | 101 | 23.7 | 59.2 | 272 | 24 |
Sb | <0.5 | <0.5 | 2.8 | 1.4 | 0.9 | 18.6 | 19.8 | 19.6 | 1.8 | 6.7 | 33.7 | 18.4 |
Ga | 17 | 18 | 13 | 14 | 16 | 19 | 19 | 28 | 30 | 18 | 2 | 4 |
Ge | 2 | 2 | 1 | 1 | 2 | 3 | 3 | 3 | 2 | 3 | 1 | 1 |
Sn | 1 | 1 | bdl | 1 | bdl | 2 | 33 | 8 | 2 | bdl | 22 | 22 |
Sb | <0.2 | <0.2 | 2.5 | 0.7 | <0.2 | 17.3 | 18.1 | 16.8 | 2.1 | 9.1 | 36.6 | 17.6 |
Bi | <0.4 | <0.4 | <0.4 | <0.4 | <0.4 | 0.9 | 34.9 | 14.8 | 5.7 | 1.6 | 132 | 27.1 |
Br | <0.5 | <0.5 | <0.5 | <0.5 | <0.5 | <0.5 | <0.5 | <0.5 | <0.5 | <0.5 | <0.5 | <0.5 |
Cr | 49 | 24 | <5 | 9 | 185 | <5 | 17 | 21 | 15 | 12 | 18 | 6 |
Ir | <5 | <5 | <5 | <5 | <5 | <5 | <5 | <5 | <5 | <5 | <5 | <5 |
Sc | 27.5 | 28 | 11.3 | 12.3 | 31 | 11.6 | 4.6 | 10.8 | 7.8 | 9.5 | 6.4 | 7.8 |
Tl | 0.1 | 0.2 | 0.3 | 0.3 | bdl | 1 | 0.2 | bdl | bdl | bdl | 1.6 | bdl |
Hf | 2.9 | 3.2 | 3.4 | 3.6 | 1.3 | 1.8 | 2.2 | 2.2 | 2.9 | 1.9 | 2.3 | 2.2 |
Ta | 0.2 | 0.7 | 0.1 | 0.1 | bdl | 0.3 | 0.3 | 0.2 | 0.2 | 0.2 | 0.3 | 0.2 |
REE (ppm) | ||||||||||||
La | 12.3 | 14.7 | 9 | 10.5 | 6.1 | 14.2 | 49.5 | 20.5 | 14.6 | 15.8 | 13.3 | 9.7 |
Ce | 27.1 | 30.3 | 21.5 | 24.7 | 13.4 | 28.1 | 101 | 40.6 | 30.4 | 32.8 | 25.1 | 18.5 |
Pr | 3.69 | 4.1 | 3.1 | 3.52 | 1.93 | 3.24 | 12.5 | 4.43 | 3.7 | 3.99 | 2.71 | 2.11 |
Nd | 15.9 | 17.5 | 14.4 | 17 | 9.4 | 12.1 | 47 | 18 | 14.8 | 15.4 | 10.3 | 8.1 |
Sm | 3.8 | 4.5 | 3.6 | 4.4 | 2.6 | 2.4 | 7.4 | 3.4 | 2.9 | 3 | 1.7 | 1.9 |
Eu | 1.01 | 1.16 | 0.79 | 1.19 | 0.89 | 0.76 | 1.39 | 0.97 | 0.86 | 0.79 | 0.41 | 0.52 |
Gd | 4 | 4.5 | 3.6 | 4.7 | 2.7 | 2.4 | 3.3 | 2.8 | 1.8 | 2.3 | 1.2 | 1.7 |
Tb | 0.7 | 0.8 | 0.7 | 0.9 | 0.5 | 0.4 | 0.3 | 0.3 | 0.2 | 0.3 | 0.1 | 0.3 |
Dy | 4.4 | 5 | 4.2 | 5.6 | 2.9 | 2.9 | 1.1 | 1.3 | 1.4 | 1.6 | 0.8 | 1.4 |
Ho | 0.9 | 1 | 0.9 | 1.2 | 0.6 | 0.6 | 0.2 | 0.2 | 0.3 | 0.3 | 0.1 | 0.2 |
Er | 2.6 | 3.1 | 2.9 | 3.7 | 1.5 | 1.5 | 0.6 | 0.6 | 1 | 0.9 | 0.4 | 0.6 |
Tm | 0.42 | 0.49 | 0.5 | 0.58 | 0.23 | 0.22 | 0.09 | 0.1 | 0.17 | 0.13 | 0.08 | 0.1 |
Yb | 2.7 | 3.4 | 3.4 | 4 | 1.5 | 1.5 | 0.6 | 0.8 | 1.4 | 0.8 | 0.6 | 0.7 |
Lu | 0.4 | 0.5 | 0.52 | 0.59 | 0.22 | 0.21 | 0.11 | 0.12 | 0.23 | 0.13 | 0.09 | 0.11 |
ΣREE | 79.92 | 91.05 | 69.11 | 82.58 | 44.47 | 70.53 | 225.09 | 94.12 | 73.76 | 78.24 | 56.89 | 45.94 |
(La/Sm)cn | 2.32 | 2.34 | 1.79 | 1.71 | 1.68 | 4.24 | 4.80 | 4.32 | 3.61 | 3.78 | 5.61 | 3.66 |
(La/Yb)cn | 3.27 | 3.10 | 1.90 | 1.88 | 2.92 | 6.79 | 59.18 | 18.38 | 7.48 | 14.17 | 15.90 | 9.94 |
(Tb/Yb)cn | 1.18 | 1.07 | 0.94 | 1.02 | 1.52 | 1.21 | 2.27 | 1.70 | 0.65 | 1.70 | 0.76 | 1.95 |
Eu/Eu* | 0.79 | 0.79 | 0.67 | 0.80 | 1.03 | 0.97 | 0.86 | 0.96 | 1.15 | 0.92 | 0.88 | 0.88 |