Sample | Heating temperature (K) for 4.20 × 102 s in air | Thickness of films (nm) by TEM observation | Compositional ratio (at%) by EDX | Mass% of oxide films and their crystallite sizes (nm) by XRD* | ||
Cu | O | Cu2O | CuO | |||
1) | 523 | around 40 | 90 | 10 | 6.0 (19.9) | 0.25 (5.1) |
2) | 573 | around 100 | 85 | 15 | 13.2 (17.4) | 0.40 (5.6) |
3) | 623 | non-uniform | 82 | 18 | 22.6 (9.2) | 6.05 (3.6) |