Primary Analyst | Recovery (%) | |||||||||||
Spiked 0.1% | Spiked 0.25% | Spiked 0.4% | ||||||||||
C14:0 | C17:0 | C18:0 | C22:6 | C14:0 | C17:0 | C18:0 | C22:6 | C14:0 | C17:0 | C18:0 | C22:6 | |
Day 1-1 | 109 | 108 | 110 | 105 | 107 | 108 | 110 | 106 | 107 | 106 | 108 | 105 |
Day 1-2 | 106 | 104 | 102 | 100 | 104 | 104 | 102 | 102 | 107 | 106 | 106 | 104 |
Day 1-3 | 109 | 110 | 110 | 108 | 108 | 107 | 105 | 104 | 106 | 105 | 105 | 103 |
Day 2-1 | 107 | 106 | 107 | 105 | 107 | 107 | 107 | 106 | 105 | 103 | 99 | 101 |
Day 2-2 | 109 | 109 | 110 | 108 | 109 | 110 | 110 | 109 | 108 | 106 | 103 | 104 |
Day 2-3 | 107 | 108 | 110 | 107 | 107 | 105 | 99 | 102 | 109 | 108 | 104 | 105 |
Day 3-1 | 100 | 102 | 109 | 100 | 107 | 108 | 106 | 102 | 108 | 108 | 101 | 102 |
Day 3-2 | 107 | 108 | 109 | 108 | 105 | 105 | 95 | 99 | 108 | 107 | 106 | 104 |
Day 3-3 | 99 | 100 | 107 | 98 | 105 | 105 | 95 | 99 | 106 | 106 | 107 | 103 |
Mean | 106 | 106 | 108 | 104 | 107 | 106 | 103 | 103 | 107 | 106 | 104 | 104 |
SD | 3.8 | 3.3 | 2.8 | 3.9 | 1.7 | 1.8 | 5.7 | 3.2 | 1.3 | 1.3 | 2.9 | 1.4 |
RSD (%) | 3.6 | 3.1 | 2.6 | 3.8 | 1.6 | 1.7 | 5.6 | 3.1 | 1.2 | 1.2 | 2.8 | 1.3 |
Secondary Analyst | C14:0 | C17:0 | C18:0 | C22:6 | C14:0 | C17:0 | C18:0 | C22:6 | C14:0 | C17:0 | C18:0 | C22:6 |
Day 1-1 | 107 | 107 | 98 | 103 | 106 | 106 | 100 | 100 | 108 | 107 | 99 | 102 |
Day 1-2 | 99 | 100 | 100 | 95 | 104 | 103 | 91 | 97 | 107 | 108 | 105 | 104 |
Day 1-3 | 99 | 100 | 101 | 96 | 106 | 107 | 100 | 102 | 106 | 107 | 107 | 103 |
Mean | 101 | 102 | 100 | 98 | 105 | 105 | 97 | 100 | 107 | 107 | 104 | 103 |
SD | 4.6 | 4.1 | 1.8 | 4.6 | 1.1 | 2.1 | 5.7 | 2.8 | 0.9 | 0.5 | 4.1 | 1.1 |
RSD (%) | 4.6 | 4.0 | 1.8 | 4.7 | 1.1 | 2 | 5.8 | 2.8 | 0.8 | 0.5 | 3.9 | 1.1 |
Relative Difference (%) to Primary Analyst | −4.2 | −3.4 | −8.1 | −6 | −1.6 | −1 | −6 | −3.3 | −0.1 | 0.8 | −0.6 | −0.6 |