Compounds

Heating rate (˚C/min)

Decomposition Temperatures (Tpv), (˚C)

Liu et al. Model prediction

Experimental values

Polystyrene

5.0

399.86

402.46

10.0

415.83

413.61

15.0

425.46

420.78

20.0

432.43

426.58

25.0

437.92

432.39

Poly(4-methylstyrene)

5.0

399.86

400.77

10.0

415.83

413.94

15.0

425.46

420.03

20.0

432.43

424.59

25.0

437.92

431.18

Poly(4-chlorostyrene)

5.0

399.86

409.21

10.0

415.83

422.21

15.0

425.46

429.84

20.0

432.43

435.18

25.0

437.92

439.76

Poly(4-bromostyrene)

5.0

399.86

406.09

10.0

415.83

415.46

15.0

425.46

423.07

20.0

432.43

429.15

25.0

437.92

432.19