Entry

Initiator

[MBL]/[I]^a

Solvent

Time (min)

Yield (g)

M_w (kDa)^b

M_n (kDa)^b

PDI^b

Tm

(˚C)

Tg

(˚C)

1

None

-

DMSO

120

0

-

-

-

-

-

2

[L^IILaN{Si(CH₃)₃}₂]THF (1)

500

DMSO

120

0

-

-

-

-

-

3

[L¹LaCl] (2)

500

DMSO

120

0.185

577

430

1.34

110

87.61

4

[L^1ILaCl] (3)

500

DMSO

120

0.100

754

570

1.32

199

123.38