Process A

Process B

Process C

Dye Aqu. Solution

Dye Aqu. Solution

Dye Aqu. Solution

Dye 0.1 g

Dye 0.1 g

Dye 0.1 g

Water 26.8 cc

Water 26.8 cc

Water 26.8 cc

PEG 0 ~ 3.1 g

PEG 0 ~ 3.1 g

Monomer Mixture

St 0.0 g

Continuous Phase

Monomer Mixture

V-65 1.0 g

Corn Oil 200 cc

St 20.0 g

POEM 1.0 g

MDI 5.0 g

V-65 1.0 g

SBL 1.0 g

POEM 1.0 g

Formation of (W/O)

SBL 1.0 g

Continuous Phase

Nr 300 rpm

MDI 0 ~ 2.0 g

Water 340 cc

t 10 min

TCP 6.0 g

T 70˚C

Continuous Phase and

Formation of (W/O)

DBS 0.2 g

Polymerization

the same ad Process A

Formation of (W/O)

Nr 300 rpm

Nr 12,000 rpm

t 24 h

Prepolymerization

t 10 min

T 7˚C

Interfacial Polym.

T 20˚C

Nr 200 rpm

t 30 min

Prepolymerization

T 70˚C

Nr 200 rpm

Prebulk Polym.

t 30 min

the same ad Process A

T 70˚C

Formation of (W/O)/W and

Polymerization

Formation of (W/O)/W and

Polymerization

the same ad Process A

Nr 300 rpm

t 8 h

T 70˚C