Process A | Process B | Process C |
Dye Aqu. Solution | Dye Aqu. Solution | Dye Aqu. Solution |
Dye 0.1 g | Dye 0.1 g | Dye 0.1 g |
Water 26.8 cc | Water 26.8 cc | Water 26.8 cc |
| PEG 0 ~ 3.1 g | PEG 0 ~ 3.1 g |
Monomer Mixture |
|
|
St 0.0 g | Continuous Phase | Monomer Mixture |
V-65 1.0 g | Corn Oil 200 cc | St 20.0 g |
POEM 1.0 g | MDI 5.0 g | V-65 1.0 g |
SBL 1.0 g |
| POEM 1.0 g |
| Formation of (W/O) | SBL 1.0 g |
Continuous Phase | Nr 300 rpm | MDI 0 ~ 2.0 g |
Water 340 cc | t 10 min |
|
TCP 6.0 g | T 70˚C | Continuous Phase and Formation of (W/O) |
DBS 0.2 g |
| |
| Polymerization | the same ad Process A |
Formation of (W/O) | Nr 300 rpm |
|
Nr 12,000 rpm | t 24 h | Prepolymerization |
t 10 min | T 7˚C | Interfacial Polym. |
T 20˚C |
| Nr 200 rpm |
|
| t 30 min |
Prepolymerization |
| T 70˚C |
Nr 200 rpm |
| Prebulk Polym. |
t 30 min |
| the same ad Process A |
T 70˚C |
|
|
|
| Formation of (W/O)/W and Polymerization |
Formation of (W/O)/W and Polymerization |
| |
| the same ad Process A | |
Nr 300 rpm |
|
|
t 8 h |
|
|
T 70˚C |
|
|