Wavenumber (cm−1)

Assignment

Ref

670

Symmetric stretching of link O-P-O in Q2 group

[56]

720

Chain type metaphosphate Q2 group

[27] [56]

770

B-O bonding in BO4 units

[57]

950

B-O bonding in BO4 units

[48] [56]

1160

symmetric stretching of non-bridging oxygen in Q2 units

[56]

1250 - 1300

asymmetric stretching vibration of non-bridging oxygen atoms in Q2 units

[58]