Compound

Online HPLC

LC-MS

Molecular formula

UVmax

(nm)

Local UVmax

(nm)

tR

(min)

[M + 1]+ m/z (observed)

Fragment

m/z

[M + 1]+ m/z

(calculated)

1

337

267

11.86

446.9725

367.0143, 287.0578

446.9692

C15H10O12S2

2

333

269

12.70

460.9869

381.0276, 301.0693

460.9848

C16H12O12S2

3

348

253, 266

13.53

449.1086

287.0562

449.1084

C21H20O11

4

349

253, 266

14.96

367.0127

287.0564

367.0124

C15H10O9S

5

338

252, 266

15.96

535.1080

-

535.1088

C24H22O14

6

330

290 (sh)

16.18

361.0929

163.0386

361.0923

C18H16O8

7

348

252, 266

17.69

381.0283

301.0719

381.0280

C16H12O9S

8

347

252, 266

17.91

381.0283

301.0719

381.0280

C16H12O9S

9

346

250, 268

20.77

287.0553

-

287.0556

C15H10O6

10*

433.1140

C21H20O10

11*

519.1155

C24H22O13

12*

549.1242

C25H24O14

13*

271.0605

C15H11O5

14*

301.0701

C16H12O6

15*

301.0701

C16H12O6