Temperature [˚C] | Gibbs free enthalpy [kcal] | |||
MnCO3 = MnO + CO2 | 2MnO + O2 = 2MnO2 | 6MnO + O2 = 2Mn3O4 | 4MnO + O2 = 2Mn2O3 | |
0 | 13.603 | −50.195 | −94.669 | −75.573 |
100 | 9.596 | −44.965 | −89.113 | −70.264 |
200 | 5.619 | −39.729 | −83.533 | −64.965 |
300 | 1.688 | −34.522 | −77.965 | −59.669 |
400 | −2.195 | −29.351 | −72.425 | −54.392 |
500 | −6.029 | −24.214 | −66.922 | −49.144 |
600 | −9.815 | −19.105 | −61.462 | −43.937 |
700 | −13.552 | −14.014 | −56.051 | −38.777 |
800 | −17.240 | −8.932 | −50.691 | −33.673 |
900 | −20.879 | −3.848 | −45.387 | −28.629 |
1000 | −24.468 | 1.250 | −40.141 | −23.65 |
Temperature [˚C] | Gibbs free enthalpy [kcal] | |||
Mn3O4 + O2 = 3MnO2 | 2Mn2O3 + O2 = 4MnO2 | MgCO3 = MgO + CO2 | CaCO3 = CaO + CO2 | |
0 | −27.958 | −24.817 | 12.649 | 32.13 |
100 | −22.891 | −19.665 | 8.457 | 28.313 |
200 | −17.827 | −14.493 | 4.293 | 24.543 |
300 | −12.801 | −9.375 | 0.172 | 20.824 |
400 | −7.815 | −4.311 | −3.9 | 17.156 |
500 | −2.861 | 0.715 | −7.914 | 13.537 |
600 | 2.073 | 5.727 | −11.866 | 9.965 |
700 | 7.004 | 10.749 | −15.751 | 6.44 |
800 | 11.947 | 15.808 | −19.563 | 2.96 |
900 | 16.922 | 20.932 | −23.299 | −0.475 |
1000 | 21.945 | 26.150 | −26.842 | −3.864 |