μ_eff B.M

Geometry

Assignments

Band position

Chemical formula

Comp. no.

--

n → π*

26,455

LH

1

π → π*

35,971

4.8

octahedral

⁴T_1g (F) → ⁴T_2g (F)

13,661

[Co₂(LH)₂Cl₄]

2

⁴T_1g (F) → ⁴A_2g (F)

13,888

⁴T_1g (F) → ⁴T_1g (P)

26,881

Charge transfer

31,645

2.82

octahedral

³A_2g (F) → ³T_2g (F)

12,820

[Ni₂(LH)₂Cl₄]

3

³A_2g (F) → ³T_1g (F)

14,025

³A_2g (F) → ³T_1g (p)

25,906

Charge transfer

37,313

1.84

octahedral

²Eg → ²T₂g

12,106

[Cu₂(LH)₂Cl₄]

4

Charge transfer

37,593

dia

octahedral

Charge transfer

26,315

[Zn₂(LH)₂Cl₄]

5

Charge transfer

28,735

dia

octahedral

Charge transfer

26,178

[Cd₂(LH)₂Cl₄]

6

Charge transfer

31,645