Wave length (nm)

E (eV)

ƒ (oscillator strength)

Major contributions

Assignments

528.78 (600)a (576)b

2.34

0.0002

H→L (39%), H−1→L (19%)

MLCT/LLCT

528.24

2.35

0.0002

H→L+1 (37%), H−1→L+1 (15%)

MLCT/LLCT

523.29

2.37

0.0002

H−2→L+1 (40%), H−1→L (23%)

MLCT/LLCT

420.72

2.95

0.0007

H→L (37%), H−2→L (12%), H−1→L+1 (12%)

MLCT/LLCT

420.30 (448)a (416)b

2.95

0.0008

H→L+1 (40%), H−1→L (12%), H−2→L+1 (11%)

MLCT/LLCT

407.38

3.04

0.0

H−2→L (33%), H−1→L+1 (32%)

MLCT/LLCT