Compound | Color | Cu site symmetry | ΔB | ΔE | ΔA | Other Transition | Reference |
CaCuO2 (infinite layer) | dark-grey | D4h | 13,230 | 15,730 | 21,370 | - | [33] |
Tenorite CuO | brownish | Ci | 12,170 | 12,930 15,530 | 16,670 | many | [53] ** |
Conichalcite synth. CaCuAsO4OH | light green | C1 | 10,575 | 12,500 | 8585 | 15,313 ZRS? 31,370 (Eg) | [54] |
Lammerite synth. Cu3(AsO4)2 | dark green | C1 Ci | 11,530 | 12,400 14,050 | 10,200 14,050 | 23,260 CuO 31,250 (Eg) | [22] ; this work* |
Y2BaCuO5 | vivid green | D4h | 12,500 | 14,700 | 25,970 CT | [55] ** | |
10,700 | 13,200 | ||||||
Azurite Cu3(CO3)2(OH)2 | blue | Ci C1 | 11,806 11,806 | 16,484 11,806 | 16,484 11,806 | 19,793 17,952 | [56] ** T = 80 K |
Chalcanthite CuSO4・5H2O | deep blue | C1 C1 | 11,407 11,860 | 13,308 13,488 | 9699 9735 | 15,234 ZRS? 15,567 | [57] |
Litidionite synth. KNaCuSi4O10 | light blue | Ci | 11,723 | 14,700 | 13,900 | 21,400 SPE 31,600 (Eg) | [22] [23] ; this work |
Cu6Ge6O18 | dirty blue | C1 | 12,100 | 14,723 | 17,700 | 22,880 SPE | [17] ; this work |
Cu6Ge6O18・6H2O | bluish-green | C1 | 11,880 | 14,320 | 11,880 | 16,230 ZRS? 21,650 CT 30,300 (Eg) | [17] ; this work |
Cu6Ge5.4Si0.6O18・6H2O | dark green | C1 | 13,300 | 19,400 | 23,900 CT | [17] | |
CuGeO3 | turquoise | D2h | 12,570 | 13,970 | 12,920 | 15,733 ZRS? 15,800 | [24] ; this work |
BaCuSi4O10 synth. (Effenbergite) | deep blue | D4h | 12,200 | 15,950 | 18,520 | - | [58] |
SrCuSi4O10 synth. (Wesselite) | 12,480 | 16,050 | 18,520 | - | [58] | ||
CaCuSi4O10 synth. (Cuprorivaite) | 12,590 12,740 | 15760 16130 | 18,530 18,520 | - | [44] [59] | ||
Dioptase dehydrated Dioptase partly dehydrated | black dark blue | C1 | 12,330 12,500 | 14,960 14,500 | 17,930 17,600 | 22,680 SPE - | This work; [19] |
Dioptase Cu6Si6O18・6H2O | emerald green | C1 | 11,500 12,495 | 14,500 15,010 | 17,000 10,200 |
| [18] [19] |
11,507 | 14,400 | 10,700 | 16,670 ZRS? 24,160 CT 30,660 (Eg) | This work |