Compound

Color

Cu site symmetry

ΔB

ΔE

ΔA

Other Transition

Reference

CaCuO2

(infinite layer)

dark-grey

D4h

13,230

15,730

21,370

-

[33]

Tenorite

CuO

brownish

Ci

12,170

12,930 15,530

16,670

many

[53] **

Conichalcite synth.

CaCuAsO4OH

light green

C1

10,575

12,500

8585

15,313 ZRS?

31,370 (Eg)

[54]

Lammerite synth.

Cu3(AsO4)2

dark green

C1

Ci

11,530

12,400

14,050

10,200 14,050

23,260 CuO

31,250 (Eg)

[22] ; this work*

Y2BaCuO5

vivid

green

D4h

12,500

14,700

25,970 CT

[55] **

10,700

13,200

Azurite

Cu3(CO3)2(OH)2

blue

Ci

C1

11,806 11,806

16,484 11,806

16,484 11,806

19,793

17,952

[56] **

T = 80 K

Chalcanthite CuSO4・5H2O

deep blue

C1

C1

11,407 11,860

13,308 13,488

9699 9735

15,234 ZRS?

15,567

[57]

Litidionite synth.

KNaCuSi4O10

light blue

Ci

11,723

14,700

13,900

21,400 SPE

31,600 (Eg)

[22] [23] ; this work

Cu6Ge6O18

dirty blue

C1

12,100

14,723

17,700

22,880 SPE

[17] ; this work

Cu6Ge6O18・6H2O

bluish-green

C1

11,880

14,320

11,880

16,230 ZRS?

21,650 CT

30,300 (Eg)

[17] ;

this work

Cu6Ge5.4Si0.6O18・6H2O

dark green

C1

13,300

19,400

23,900 CT

[17]

CuGeO3

turquoise

D2h

12,570

13,970

12,920

15,733 ZRS? 15,800

[24] ; this work

BaCuSi4O10 synth. (Effenbergite)

deep blue

D4h

12,200

15,950

18,520

-

[58]

SrCuSi4O10 synth. (Wesselite)

12,480

16,050

18,520

-

[58]

CaCuSi4O10 synth. (Cuprorivaite)

12,590 12,740

15760 16130

18,530

18,520

-

[44]

[59]

Dioptase dehydrated

Dioptase partly dehydrated

black dark blue

C1

12,330

12,500

14,960

14,500

17,930

17,600

22,680 SPE

-

This work;

[19]

Dioptase

Cu6Si6O18・6H2O

emerald green

C1

11,500 12,495

14,500 15,010

17,000 10,200

[18]

[19]

11,507

14,400

10,700

16,670 ZRS?

24,160 CT

30,660 (Eg)

This work