Cu6Si6O18・6H2O (dioptase)

Cu6Ge6O18・6H2O (Ge-dioptase)

P

λ(nm)

Γ(nm)

E(cm−1)

Assignment

P

λ(nm)

Γ(nm)

E(cm−1)

Assignment

329

935 ± 37

208

10,700

ΔA

1000

842 ± 30

198

11,884

ΔB + ΔA

815

869 ± 12

208

11,507

ΔB

1000

695 ± 7

194

14,400

ΔE

645

698 ± 24

166

14,321

ΔE

256

600

109

16,670

ZRS?

185

616

129

16,230

ZRS?

421

414

108

24,160

SPE?

271

462

147

21,650

SPE?

(554)

326

102

30,660

Eg

(531)

353

97

28,350

Eg

Cu6Si6O18 (dioptase dehydrated)

Cu6Ge6O18 (Ge-dioptase dehydrated)

P

λ(nm)

Γ(nm)

E(cm−1)

Assignment

P

λ (nm)

Γ(nm)

E(cm−1)

Assignment

1000

811 ± 14

158

12,330

ΔB

1000

827 ± 14

155

12,100

ΔB

866

668 ± 12

120

14,960

ΔE

843

679 ± 12

127

14,723

ΔE

492

558 ± 11

96

17,930

ΔA

450

565 ± 12

97

17,700

ΔA

235

441

100

22,680

SPE?

355

437

108

22,880

SPE?

(869)

330

120

30,300

Eg

(630)

357

102

28,000

Eg