Rock sample No. | Shales | Calcareous shales | Sandstones | Lt Soil | ||||||||||||||||
S5 | S19 | S23 | S25 | S29 | S30 | S31 | S33 | S39 | S11 | S15 | S17 | S21 | S38 | S2 | S9 | S12 | S28 | S32 | S8 | |
SiO2 | 50.57 | 61.77 | 51.90 | 58.09 | 69.9 | 72.2 | 70.5 | 51.1 | 47.6 | 47.2 | 49.3 | 29.0 | 30.6 | 44.6 | 84 | 85.2 | 72.5 | 53.17 | 94.37 | 28.9 |
TiO2 | 2.21 | 0.90 | 1.94 | 3.04 | 2.40 | 2.88 | 0.77 | 2.50 | 2.22 | 1.55 | 2.15 | 1.0 | 1.09 | 1.70 | 0.5 | 1.59 | 0.69 | 0.27 | 0.20 | 1.2 |
Al2O3 | 18.89 | 7.68 | 15.05 | 14.90 | 11.3 | 12.1 | 11.6 | 18.9 | 17.6 | 17.2 | 16.3 | 6.42 | 6.77 | 15.8 | 3.7 | 8.37 | 11.1 | 2.12 | 3.68 | 12.32 |
Fe2O3 | 5.39 | 13.72 | 11.40 | 5.65 | 3.68 | 5.31 | 2.94 | 6.49 | 10.3 | 10.4 | 11.6 | 7.62 | 6.76 | 17.4 | 8.3 | 0.43 | 2.38 | 36.81 | 0.17 | 43.43 |
MnO | 0.02 | 0.05 | 0.07 | 0.03 | 0.02 | <0.01 | 0.02 | 0.03 | 0.03 | 0.05 | 0.05 | 0.08 | 0.08 | 0.05 | 0.01 | <0.01 | <0.01 | <0.01 | <0.01 | 0.10 |
MgO | 0.91 | 1.94 | 1.53 | 0.43 | 0.10 | 0.09 | 0.40 | 0.50 | 1.23 | 1.52 | 1.57 | 1.45 | 1.30 | 2.36 | 0.02 | 0.06 | 0.4 | <0.01 | <0.01 | 0.09 |
CaO | 0.24 | 2.75 | 0.50 | 0.13 | 0.03 | <0.01 | 0.06 | 0.07 | 0.65 | 3.98 | 0.97 | 27.5 | 26.5 | 1.53 | 0.14 | 0.21 | 0.69 | 0.05 | <0.01 | 0.44 |
Na2O | 0.38 | 0.16 | 0.45 | 0.56 | 0.07 | 0.03 | 0.10 | 0.08 | 0.24 | 0.27 | 0.45 | 0.28 | 0.28 | 0.17 | 0.02 | 0.02 | 0.29 | <0.01 | <0.01 | <0.01 |
K2O | 2.04 | 0.90 | 2.76 | 3.15 | 1.78 | 0.54 | 2.57 | 2.26 | 2.28 | 2.11 | 2.68 | 1.8 | 1.84 | 1.53 | 0.03 | 0.17 | 2.29 | 0.01 | 0.02 | 0.1 |
P2O5 | 0.08 | 1.24 | 0.08 | 0.06 | 0.14 | 0.12 | 0.04 | 0.08 | 0.08 | 0.10 | 0.06 | 0.07 | 0.06 | 0.08 | 0.05 | <0.01 | 0.06 | 0.26 | 0.02 | 0.59 |
Cr2O3 | 0.01 | 0.04 | 0.02 | 0.021 | 0.02 | 0.02 | 0.01 | 0.02 | 0.02 | 0.02 | 0.02 | 0.01 | 0.01 | 0.02 | 0.01 | 0.01 | 0.01 | 0.01 | <0.002 | 0.07 |
LOI | 19.00 | 8.50 | 13.90 | 13.6 | 10.1 | 6.4 | 10.7 | 17.6 | 17.6 | 15.3 | 14.6 | 24.4 | 24.4 | 14.5 | 2.8 | 3.8 | 9.4 | 7.3 | 1.6 | 12.5 |
Total | 99.743 | 99.646 | 99.60 | 99.66 | 99.5 | 99.7 | 99.7 | 99.6 | 99.8 | 99.7 | 99.7 | 99.6 | 99.7 | 99.7 | 99.9 | 99.8 | 99.8 | 99.99 | 100.06 | 99.74 |
Ni | 34 | 25 | 57 | 27 | <20 | <20 | <20 | 48 | 67 | 57 | 37 | <20 | <20 | 80 | <20 | <20 | <20 | <20 | <20 | 32 |
Sc | 13 | 12 | 13 | 13 | 9 | 10 | 6 | 13 | 15 | 13 | 14 | 8 | 7 | 16 | 3 | 5 | 5 | 7 | <1 | 20 |
Ba | 688 | 283 | 809 | 812 | 1378 | 693 | 1142 | 897 | 593 | 681 | 743 | 527 | 558 | 578 | 26 | 88 | 662 | 7 | 26 | 65 |
Be | 3 | 2 | 4 | 3 | 2 | 2 | 1 | 4 | 4 | 4 | <1 | 1 | 1 | <1 | 2 | <1 | <1 | 1 | 1 | 7 |
Co | 12.4 | 20.8 | 48.1 | 9.4 | 12.0 | 1.8 | 8.5 | 24.3 | 29.2 | 30.2 | 33.4 | 20.8 | 20.4 | 40.0 | 2.7 | 0.5 | 10.3 | 0.5 | 0.3 | 29.3 |
Cs | 1.9 | 0.7 | 1.4 | 1.0 | 0.7 | 0.3 | 0.5 | 1.9 | 1.3 | 1.8 | 1.8 | 0.6 | 0.6 | 1.6 | 0.1 | <0.1 | 0.9 | <0.1 | <0.1 | 0.6 |
Ga | 28.6 | 13.1 | 24.8 | 25.6 | 14.8 | 16.2 | 12.5 | 27.6 | 23.7 | 24.6 | 24.4 | 9.7 | 10.0 | 23.3 | 3.4 | 8.2 | 13.4 | 3.8 | 3.1 | 19.4 |
Hf | 18.4 | 12.5 | 20.7 | 25.9 | 46.4 | 39.6 | 20.5 | 31.4 | 17.5 | 11.6 | 15.4 | 21.1 | 22.7 | 13.5 | 2.9 | 26.4 | 6.3 | 4.1 | 3.1 | 21.2 |
Nb | 65.6 | 29.6 | 54.0 | 71.4 | 53.7 | 61.3 | 21.4 | 89.3 | 48.5 | 43.4 | 45.5 | 26 | 35.9 | 40.5 | 13 | 32.5 | 18.9 | 7.1 | 6.1 | 31.7 |
Rb | 57.9 | 24.6 | 69.6 | 69.0 | 42.3 | 16.1 | 48.3 | 58.9 | 55.0 | 55.2 | 63.4 | 39 | 38.3 | 38.0 | 1.5 | 4.9 | 48.9 | 0.9 | 0.5 | 7.3 |
Sn | 6 | 3 | 4 | 7 | 3 | 4 | <1 | 7 | 4 | 5 | 6 | 2 | 2 | 4 | <1 | 2 | 2 | <1 | <1 | 3 |
Sr | 96.6 | 160.7 | 139.3 | 108.8 | 206 | 128 | 162 | 136 | 121 | 269 | 149 | 838 | 737 | 141 | 13 | 13.7 | 107 | 6.3 | 4.0 | 30.9 |
Ta | 4.4 | 4.3 | 3.2 | 3.8 | 3.2 | 3.8 | 1.0 | 5.9 | 2.7 | 7.5 | 2.2 | 1.4 | 2.3 | 2.6 | 1 | 3.5 | 2.3 | 0.5 | 0.4 | 2.2 |
Th | 19.5 | 18 | 18.3 | 20.2 | 20.7 | 21.4 | 10.8 | 24.6 | 19.2 | 17.5 | 17.8 | 12 | 11.5 | 16.9 | 4.9 | 11.1 | 7.4 | 3.4 | 1.3 | 19.1 |
U | 4.6 | 6.5 | 3.5 | 4.4 | 6.7 | 6.1 | 2.9 | 6.5 | 4.4 | 3.3 | 3.5 | 2.7 | 3.0 | 3.5 | 0.9 | 2.1 | 1.4 | 3.2 | 0.4 | 8.6 |
V | 109 | 399 | 181 | 157 | 96 | 119 | 41 | 121 | 144 | 228 | 189 | 105 | 90 | 182 | 27 | 57 | 82 | 37 | 9 | 524 |
W | 1.3 | <0.5 | 1.5 | 1.9 | 1.2 | 1.0 | 0.7 | 1.4 | 1.2 | 1.2 | 1.2 | <0.5 | 1.3 | 1.7 | <0.5 | 1.5 | 0.8 | <0.5 | <0.5 | 0.9 |
Zr | 703.7 | 470.9 | 772.2 | 972.6 | 1746 | 1425 | 801 | 1114 | 649 | 447 | 565 | 794 | 830 | 537 | 98.9 | 1012 | 227.8 | 181.2 | 136.9 | 843.5 |
La | 76.50 | 95.40 | 77.30 | 66.20 | 45.1 | 41.9 | 29.0 | 79.5 | 67.3 | 66.9 | 60.7 | 64.1 | 53.5 | 77.8 | 9.6 | 12.4 | 56.7 | 7.7 | 2.2 | 36 |
Ce | 156.1 | 231.10 | 177.50 | 151.0 | 94.3 | 84.0 | 60.4 | 170.8 | 137.8 | 145.3 | 136.4 | 145.9 | 122.9 | 165.7 | 46 | 24.2 | 101 | 14.2 | 5.0 | 110.8 |
Pr | 18.41 | 26.14 | 19.69 | 16.33 | 10.1 | 9.09 | 6.77 | 18.49 | 15.82 | 17.28 | 15.95 | 16.4 | 13.16 | 19.32 | 1.9 | 2.84 | 13.8 | 1.56 | 0.45 | 7.71 |