| № |
Reaction |
Temperature, K |
|||||||
| 293 |
313 |
353 |
373 |
||||||
| ΔG˚ |
LgK |
ΔG˚ |
LgK |
ΔG˚ |
LgK |
ΔG˚ |
LgK |
||
| 1 |
NiCl2 + H2S + Fe = NiS + FeCl2 + H2 |
−94.8 |
16.9 |
−94.3 |
15.7 |
−93.2 |
13.8 |
−92.7 |
13.0 |
| 2 |
FeS + NiCl2 = NiS + FeCl2 |
−26.0 |
4.6 |
−26.2 |
4.4 |
−26.8 |
4.0 |
−27.0 |
3.8 |
| 3 |
Fe7S8 + 7NiCl2 = 7NiS + 7FeCl2 + S |
−146.9 |
26.4 |
−149.3 |
24.9 |
−151.7 |
22.4 |
−152.9 |
21.4 |
| 4 |
NiCl2 + Fe = Ni + FeCl2 |
−42.7 |
7.6 |
−43.1 |
7.2 |
−44.1 |
6.5 |
−44.6 |
6.2 |
| 5 |
Fe2S3 + 2NiCl2 = 2NiS + 2FeCl2 + S |
24.5 |
−4.4 |
23.9 |
−4.0 |
22.5 |
−3.3 |
21.7 |
−3.0 |
| 6 |
NiCl2 + FeS2 = NiS + FeCl2 + S |
31.1 |
−5.5 |
30.0 |
−5.0 |
27.8 |
−4.1 |
26.7 |
−3.7 |