Calculated Frequencies (cm−1) | Vibrational Assignment |
3707.1 | (N?H)pyrazole stretching vibration |
3279.2 | (C?H)pyrazole stretching vibration |
3230.3 | (C?H)benzene stretching vibration |
3114.4 | (C?H)cyclohexane anti-symmetric stretching |
1661.5 | (C?C,C=C)cyclohexane, benzene anti-symmetric stretching |
1501.0 | (C?H)cyclohexane, benzene scissoring |
1435.3 | (C=C)pyrazole stretching |
1377.6 | (NO3−)uncoordinated anti-symmetric stretching |
1324.1 | (C?H)cyclohexane, benzene rocking |
1095.7 | (C=N, N?N)pyrazole symmetric stretching |
1062.3 | (C?C)cyclohexane twisting |
1033.1 | (C=C)benzene twisting |
979.3 | Ag?Npyrazole symmetric stretching |
968.4 | (C?H)pyrazole rocking |
959.8 | (NO3−)uncoordinated symmetric stretching |
802.9 | (C?H)benzene wagging |
720.5 | (NO3−)uncoordinated wagging |
647.7 | (NO3−)uncoordinated scissoring |
574.1 | (N?H)pyrazole rocking |
434.1 | (C?C)cyclohexane scissoring |
183.4 | Ag?Npyrazole anti-symmetric stretching |