Lengths (Å) | |||
Pt(1)-O(5) | 2.023(13) | W(1)-O(3) | 1.743(17) |
Pt(1)-O(10) | 2.040(2) | W(2)-O(5) | 1.746(14) |
Pt(2)-O(3) | 2.030(17) | W(5)-O(11) | 1.700(2) |
Pt(2)-O(11) | 2.060(2) | W(6)-O(10) | 1.680(2) |
Average | 2.038 | Average | 1.717 |
Pt(1)-N(1) | 2.000(2) | W(1)-O(4) | 1.900(2) |
Pt(1)-N(2) | 2.040(3) | W(2)-O(4) | 1.950(19) |
Pt(2)-N(3) | 2.030(2) | W(5)-O(19) | 1.923(19) |
Pt(2)-N(4) | 2.040(3) | W(6)-O(19) | 1.950(2) |
Average | 2.028 | Average | 1.931 |
|
| Pt(1)×××Pt(2) | 3.300 |
Angles (˚) | |||
Pt(1)-O(5)-W(2) | 160.7(10) | Pt(2)-O(3)-W(1) | 163.3(11) |
Pt(1)-O(10)-W(6) | 155.4(10) | Pt(2)-O(11)-W(5) | 154.2(11) |
Average | 158.1 | Average | 158.8 |
O(5)-Pt(1)-O(10) | 90.2(7) | O(3)-Pt(2)-O(11) | 89.1(8) |
O(5)-Pt(1)-N(2) | 85.6(8) | O(3)-Pt(2)-N(4) | 87.1(10) |
O(10)-Pt(1)-N(1) | 88.7(9) | O(11)-Pt(2)-N(3) | 91.7(10) |
N(1)-Pt(1)-N(2) | 95.2(10) | N(3)-Pt(2)-N(4) | 91.9(11) |
Average | 89.9 | Average | 90.0 |
W(1)-O(4)-W(2) | 146.3(10) | W(5)-O(19)-W(6) | 117.0(9) |