Lengths (Å) | |||
Pt(1)-O(5) | 1.978(9) | W(1)-O(3) | 1.851(9) |
Pt(1)-O(10) | 1.997(12) | W(2)-O(5) | 1.784(9) |
Pt(2)-O(3) | 1.907(9) | W(5)-O(11) | 1.775(11) |
Pt(2)-O(11) | 1.990(11) | W(6)-O(10) | 1.780(11) |
Average | 1.968 | Average | 1.798 |
Pt(1)-N(1) | 2.004(11) | W(1)-O(4) | 1.920(10) |
Pt(1)-N(2) | 2.032(15) | W(2)-O(4) | 1.884(11) |
Pt(2)-N(3) | 1.995(11) | W(5)-O(19) | 1.922(11) |
Pt(2)-N(4) | 2.020(14) | W(6)-O(19) | 1.922(9) |
Average | 2.013 | Average | 1.912 |
|
| Pt(1)×××Pt(2) | 3.275 |
Angles (˚) | |||
Pt(1)-O(5)-W(2) | 165.3(6) | Pt(2)-O(3)-W(1) | 160.2(7) |
Pt(1)-O(10)-W(6) | 153.9(6) | Pt(2)-O(11)-W(5) | 151.5(5) |
Average | 159.6 | Average | 155.9 |
O(5)-Pt(1)-O(10) | 90.3(4) | O(3)-Pt(2)-O(11) | 91.6(4) |
O(5)-Pt(1)-N(2) | 88.0(5) | O(3)-Pt(2)-N(4) | 86.8(5) |
O(10)-Pt(1)-N(1) | 89.4(5) | O(11)-Pt(2)-N(3) | 86.6(5) |
N(1)-Pt(1)-N(2) | 92.2(5) | N(3)-Pt(2)-N(4) | 94.8(5) |
Average | 90.0 | Average | 90.0 |
W(1)-O(4)-W(2) | 147.7(6) | W(5)-O(19)-W(6) | 117.8(5) |