Lengths (Å) | |||
Pt(1)-O(5) | 2.021(13) | W(1)-O(3) | 1.729(13) |
Pt(1)-O(10) | 1.997(11) | W(2)-O(5) | 1.756(13) |
Pt(2)-O(3) | 2.049(13) | W(5)-O(11) | 1.793(13) |
Pt(2)-O(11) | 1.999(13) | W(6)-O(10) | 1.792(11) |
Average | 2.017 | Average | 1.768 |
Pt(1)-N(1) | 2.030(16) | W(1)-O(4) | 1.932(11) |
Pt(1)-N(2) | 2.054(16) | W(2)-O(4) | 1.886(12) |
Pt(2)-N(3) | 2.028(17) | W(5)-O(19) | 1.924(13) |
Pt(2)-N(4) | 2.057(17) | W(6)-O(19) | 1.958(11) |
Average | 2.042 | Average | 1.925 |
|
| Pt(1)×××Pt(2) | 3.267 |
Angles (˚) | |||
Pt(1)-O(5)-W(2) | 162.8(7) | Pt(2)-O(3)-W(1) | 164.0(8) |
Pt(1)-O(10)-W(6) | 153.4(7) | Pt(2)-O(11)-W(5) | 154.0(9) |
Average | 158.1 | Average | 159.0 |
O(5)-Pt(1)-O(10) | 91.3(5) | O(3)-Pt(2)-O(11) | 92.2(6) |
O(5)-Pt(1)-N(2) | 87.8(6) | O(3)-Pt(2)-N(4) | 86.7(6) |
O(10)-Pt(1)-N(1) | 87.0(6) | O(11)-Pt(2)-N(3) | 88.1(7) |
N(1)-Pt(1)-N(2) | 93.9(7) | N(3)-Pt(2)-N(4) | 93.0(7) |
Average | 90.0 | Average | 90.0 |
W(1)-O(4)-W(2) | 147.5(7) | W(5)-O(19)-W(6) | 121.6(6) |