Solutionsb)
G
(mmol)
X
(mmol)
X/catalyst
(mol/mol)
Irradn. Time
(h)c)
Volume (mL)
Molar ratio
(mol/mol)
e)
(yield/%) [WH/mg]
Totald)
H2
CO2
H2/X
CO2/X
Solution A
(a = 2.392) [38.7]
0.206
0.086
0.069
100
74
49
25
25.4
13.0
30.6
(79.0) [78.7]
0.299
0.125
0.100
72
88
59
29
21.1
10.4
0.421
0.176
0.141
114
92
61
31
15.5
7.86
0.598
0.250
0.200
120
90
60
30
10.7
5.4
0.751
0.314
0.251
192
86
57
29
8.10
4.12
Solution B
(a = 2.063) [34.8]
0.166
0.081
0.064
75
78
52
26
28.9
14.4
32.0
(91.9) [84.0]
0.292
0.142
0.113
140
134
89
45
28.2
14.1
0.417
0.203
0.162
119
156
104
52
23.0
11.5
0.600
0.292
0.233
216
182
121
61
18.6
9.3
0.800
0.389
0.310
124
240
160
80
18.4
9.2
Solution C
(a = 0.133) [11.60]
0.033
0.290
0.120
72
80
53
27
8.16
4.16
10.7
(92.2) [17.3]
0.069
0.520
0.232
171
115
77
38
6.61
3.26
0.100
0.750
0.416
128
150
100
50
5.95
2.98
0.133
1.000
0.600
163
90
60
30
2.68
1.34
Solution D
(a = 0.07) [10.84]
0.018
0.250
0.200
115
64
43
21
7.62
3.81
9.42
(86.9) [21.0]
0.035
0.500
0.400
290
112
75
37
6.67
3.34
0.053
0.750
0.600
188
95
63
32
3.37
1.69
0.070
1.000
0.800
165
84
56
28
2.50
1.25
0.088
1.250
1.000
190
46
31
15
1.10
0.55