grain/ domain

comment

176Yb/177Hfa

±2σ

176Lu/177Hfa

±2σ

178Hf/177Hf

180Hf/177Hf

SigHfb

(V)

176Hf/177Hf

±2σc

176Hf/ 177Hf(t)d

εHf(t)d

±2σc

TDM2e

(Ga)

agef

(Ma)

±2σ

conc.g

Sample 1, tonalite (NG14-02)

zA8

m

0.0098

0

0.00035

0

1.46724

1.88692

16

0.282626

30

0.282622

8.7

1.1

1.03

650

10

98

zA9

m

0.0141

4

0.00049

1

1.46723

1.88687

15

0.282624

28

0.282618

8.7

1.0

1.03

655

10

101

zA10

m

0.0094

0

0.00035

0

1.46730

1.88683

19

0.282619

28

0.282615

7.7

1.0

1.06

616

9

99

zA11

m

0.0158

3

0.00059

1

1.46726

1.88700

15

0.282606

27

0.282599

7.8

0.9

1.08

645

9

95

zA12

m

0.0083

1

0.00031

0

1.46726

1.88695

17

0.282618

27

0.282614

8.7

0.9

1.04

657

10

100

zA13

m

0.0074

1

0.00027

0

1.46722

1.88674

16

0.282595

27

0.282592

7.6

1.0

1.09

646

10

86

zA14

m

0.0079

2

0.00030

1

1.46728

1.88700

17

0.282625

28

0.282622

8.9

1.0

1.02

658

10

99

zA15

m

0.0073

1

0.00031

0

1.46731

1.88684

20

0.282626

28

0.282622

8.6

1.0

1.03

644

10

98

zA16

m

0.0079

1

0.00029

0

1.46723

1.88682

15

0.282644

29

0.282640

9.1

1.0

1.00

637

12

95

zA17

m

0.0143

2

0.00050

1

1.46728

1.88681

17

0.282631

28

0.282625

8.4

1.0

1.03

631

9

95

zA18

m

0.0082

1

0.00032

0

1.46728

1.88683

17

0.282633

27

0.282630

8.3

0.9

1.03

619

11

98

zA19

m

0.0145

5

0.00052

2

1.46727

1.88671

16

0.282618

29

0.282612

7.9

1.0

1.06

627

18

93

zA20

m

0.0151

13

0.00053

4

1.46729

1.88688

15

0.282640

29

0.282633

9.2

1.0

1.01

651

12

100

zA21

m

0.0184

19

0.00065

7

1.46726

1.88683

15

0.282615

31

0.282607

8.3

1.1

1.06

652

11

101

zA22

m

0.0123

3

0.00043

1

1.46723

1.88669

15

0.282614

36

0.282608

8.0

1.3

1.06

637

9

98

zA23

m

0.0154

5

0.00055

2

1.46726

1.88673

15

0.282620

31

0.282613

8.4

1.1

1.05

650

11

99

zA24

m

0.0132

4

0.00047

2

1.46725

1.88675

16

0.282619

28

0.282613

8.5

1.0

1.04

653

11

100

zA25

m

0.0177

5

0.00067

2

1.46725

1.88666

15

0.282615

28

0.282607

8.0

1.0

1.06

638

11

94

(a) 176Yb/177Hf = (176Yb/173Yb)true × (173Yb/177Hf)meas × (M173(Yb)/M177(Hf))b(Hf), b(Hf) = ln(179Hf/177Hftrue/179Hf/177Hfmeasured)/ln(M179(Hf)/M177(Hf)).

M = mass of respective isotope. The 176Lu/177Hf were calculated in a similar way by using the 175Lu/177Hf and b(Yb).

Quoted uncertainties (absolute) relate to the last quoted figure. The effect of the inter-element fractionation on the Lu/Hf was estimated to be about 6 % or less based on analyses of the GJ-1 and Plesoviče zircons.

(b) Mean Hf signal in volt.

(c) Uncertainties are quadratic additions of the within-run precision and the daily reproducibility of the zircon GJ-1. Uncertainties for GJ-1 is 2SD (2 standard deviation).

(d) Initial 176Hf/177Hf and Hf calculated using the age (Ma). and the CHUR parameters: 176Lu/177Hf = 0.0336. and 176Hf/177Hf = 0.282785 (Bouvier et al. 2008) .

(e) two stage model age in billion years using the measured 176Lu/177Lu.thestimated age (Ma). a value of 0.01113 for the averageconinental crust (second stage). and a depleted mantle 176Lu/177Hf and 176Hf/177Hf of 0.03933 and 0.283294.

(f) 206Pb/238U age for zircon < 1.0 Ga. and 206Pb/207Pb age for zircon > 1.0 Ga.

(g) degree of concordance

results of standard measurements 22-01-2015

zircon standard GJ1

GJ1-40-1

0.0066

0.5

0.00023

0.04

1.46725

1.88628

8

0.281995

29

0.281992

−14.5

1.0

2.27

606

GJ1-40-2

0.0068

0.5

0.00024

0.03

1.46725

1.88619

8

0.282012

34

0.282010

−13.9

1.2

2.24

606

GJ1-40-3

0.0071

0.6

0.00025

0.05

1.46731

1.88609

8

0.282025

33

0.282023

−13.5

1.2

2.21

606

GJ1-40-4

0.0068

0.4

0.00025

0.05

1.46729

1.88633

7

0.282009

34

0.282006

−14.0

1.2

2.24

606

GJ1-40-5

0.0069

0.2

0.00025

0.04

1.46726

1.88621

7

0.282005

33

0.282002

−14.2

1.2

2.25

606

GJ1-40-6

0.0068

0.6

0.00024

0.06

1.46732

1.88640

8

0.282012

35

0.282009

−13.9

1.2

2.24

606

GJ1-40-7

0.0074

1.0

0.00025

0.04

1.46735

1.88647

12

0.282009

29

0.282006

−14.0

1.0

2.24

606

GJ1-40-8

0.0072

0.6

0.00025

0.06

1.46733

1.88650

12

0.282001

31

0.281998

−14.3

1.1

2.26

606

GJ1-40-9

0.0073

0.7

0.00025

0.05

1.46724

1.88642

12

0.282002

29

0.281999

−14.3

1.0

2.25

606

GJ1-40-10

0.0069

0.4

0.00025

0.06

1.46717

1.88647

6

0.281990

39

0.281987

−14.7

1.4

2.28

606

GJ1-40-11

0.0068

0.4

0.00025

0.08

1.46720

1.88643

6

0.281994

31

0.281992

−14.6

1.1

2.27

606

GJ1-40-12

0.0069

0.3

0.00025

0.05

1.46729

1.88668

11

0.281981

30

0.281978

−15.0

1.1

2.30

606

GJ1-40-13

0.0070

0.4

0.00024

0.02

1.46727

1.88632

14

0.281982

32

0.281980

−15.0

1.1

2.29

606

GJ1-40-14

0.0070

0.3

0.00025

0.03

1.46730

1.88643

13

0.282002

31

0.281999

−14.3

1.1

2.26

606

GJ1-40-15

0.0071

0.3

0.00025

0.03

1.46735

1.88640

14

0.281986

29

0.281983

−14.9

1.0

2.29

606

GJ1-40-16

0.0068

0.3

0.00025

0.06

1.46726

1.88643

12

0.282001

29

0.281998

−14.3

1.0

2.26

606

GJ1-40-17

0.0068

0.2

0.00025

0.05

1.46725

1.88623

6

0.282010

35

0.282008

−14.0

1.3

2.24

606

GJ1-40-18

0.0069

0.3

0.00025

0.06

1.46729

1.88612

6

0.281991

32

0.281988

−14.7

1.1

2.28

606

GJ1-40-19

0.0070

0.5

0.00025

0.04

1.46730

1.88638

12

0.281992

31

0.281989

−14.6

1.1

2.27

606

mean (n = 19)

0.0070

0.00025

1.46728

1.88636

0.281997

−14.4

2 S.D.

0.0004

0.00001

0.00009

0.00029

0.000023

0.8

zircon standard Plesovice

Pleso1

0.0039

0.2

0.00010

0.06

1.46729

1.88636

11

0.282441

28

0.282440

−4.7

1.0

1.52

337

Pleso2

0.0041

0.3

0.00010

0.09

1.46729

1.88646

11

0.282453

29

0.282452

−4.3

1.0

1.50

337

Pleso3

0.0039

0.1

0.00009

0.04

1.46731

1.88651

12

0.282434

29

0.282434

−4.9

1.0

1.53

337

Pleso4

0.0041

1.0

0.00010

0.26

1.46737

1.88658

25

0.282494

26

0.282494

−2.8

0.9

1.42

337

Pleso5

0.0039

1.2

0.00010

0.29

1.46727

1.88638

10

0.282449

33

0.282448

−4.4

1.2

1.51

337

Pleso6

0.0038

1.0

0.00009

0.25

1.46733

1.88636

11

0.282471

31

0.282470

−3.6

1.1

1.46

337

Pleso7

0.0055

0.6

0.00013

0.09

1.46735

1.88673

16

0.282479

29

0.282478

−3.3

1.0

1.45

337

Pleso8

0.0040

0.6

0.00010

0.12

1.46735

1.88651

17

0.282490

29

0.282489

−3.0

1.0

1.43

337

mean (n = 8)

0.0041

0.00010

1.46732

1.88649

0.282463

−3.9

2 S.D.

0.0011

0.00002

0.00007

0.00025

0.000046

1.6

zircon standard 91500

91500-1

0.0086

1

0.00031

0.2

1.46736

1.88651

5

0.282302

39

0.282296

6.6

1.4

1.47

1065

91500-2

0.0087

1

0.00031

0.3

1.46724

1.88630

7

0.282327

37

0.282321

7.5

1.3

1.43

1065

91500-3

0.0089

1

0.00032

0.2

1.46731

1.88665

14

0.282288

30

0.282282

6.1

1.1

1.50

1065

91500-4

0.0091

1

0.00032

0.3

1.46741

1.88664

12

0.282326

30

0.282319

7.4

1.1

1.43

1065

91500-5

0.0093

2

0.00033

0.5

1.46730

1.88643

12

0.282323

28

0.282316

7.3

1.0

1.43

1065

91500-6

0.0091

1

0.00030

0.1

1.46728

1.88644

9

0.282293

30

0.282287

6.3

1.1

1.49

1065

91500-7

0.0090

1

0.00031

0.3

1.46733

1.88660

9

0.282325

32

0.282319

7.4

1.1

1.43

1065

mean (n = 7)

0.0089

0.00031

1.46732

1.88651

0.282306

6.9

2 S.D.

0.0005

0.00002

0.00011

0.00026

0.000034

1.2

zircon standard Temora

Temora1

0.0214

5

0.00077

1.7

1.46729

1.88665

8

0.282671

32

0.282665

3.7

1.1

1.13

419

Temora2

0.0291

3

0.00104

1.1

1.46731

1.88659

8

0.282664

32

0.282656

3.4

1.1

1.14

419

Temora3

0.0130

4

0.00047

1.6

1.46727

1.88666

9

0.282677

31

0.282674

4.0

1.1

1.11

419

Temora4

0.0232

0

0.00080

0.2

1.46735

1.88670

8

0.282693

33

0.282687

4.5

1.2

1.08

419

Temora5

0.0278

18

0.00096

6.4

1.46735

1.88619

7

0.282692

37

0.282684

4.4

1.3

1.09

419

Temora6

0.0324

11

0.00115

3.4

1.46737

1.88654

7

0.282692

36

0.282683

4.3

1.3

1.09

419

Temora7

0.0237

4

0.00077

1.7

1.46733

1.88654

6

0.282694

41

0.282688

4.5

1.4

1.08

419

mean (n = 7)

0.0244

0.00085

1.46732

1.88655

0.282677

4.1

2 S.D.

0.0126

0.00044

0.00007

0.00034

0.000025

0.9

results of standard measurements 23-01-2015

zircon standard GJ1

GJ-50-1

0.0068

0.4

0.00025

0.06

1.46727

1.88670

16

0.282013

35

0.282011

−13.9

1.2

2.23

606

1

GJ-50-2

0.0068

0.3

0.00025

0.05

1.46729

1.88696

16

0.282000

35

0.281997

−14.4

1.2

2.26

606

1

GJ-50-3

0.0069

0.3

0.00025

0.05

1.46723

1.88674

17

0.281998

37

0.281995

−14.4

1.3

2.26

606

1

GJ-50-4

0.0069

0.4

0.00025

0.06

1.46731

1.88677

16

0.281981

33

0.281979

−15.0

1.2

2.29

606

1

GJ-50-5

0.0068

0.3

0.00025

0.05

1.46729

1.88677

16

0.282010

34

0.282007

−14.0

1.2

2.24

606

1

GJ-50-6

0.0070

0.3

0.00025

0.03

1.46728

1.88667

16

0.281984

35

0.281981

−14.9

1.2

2.29

606

1

GJ-50-7

0.0069

0.3

0.00025

0.05

1.46735

1.88675

12

0.282022

36

0.282019

−13.6

1.3

2.22

606

1

GJ-50-8

0.0069

0.2

0.00025

0.05

1.46735

1.88676

12

0.282029

35

0.282027

−13.3

1.2

2.20

606

1

GJ-50-9

0.0070

0.3

0.00025

0.04

1.46732

1.88683

13

0.282013

34

0.282010

−13.9

1.2

2.23

606

1

GJ-50-12

0.0070

0.4

0.00025

0.04

1.46725

1.88689

9

0.281992

36

0.281990

−14.6

1.3

2.27

606

1

GJ-50-13

0.0069

0.3

0.00025

0.06

1.46722

1.88660

9

0.281988

36

0.281985

−14.8

1.3

2.28

606

1

GJ-50-14

0.0070

0.2

0.00025

0.04

1.46717

1.88680

9

0.281973

38

0.281970

−15.3

1.4

2.31

606

1

GJ-50-15

0.0070

0.4

0.00025

0.05

1.46717

1.88670

9

0.282014

36

0.282011

−13.9

1.3

2.23

606

1

GJ-50-16

0.0071

0.5

0.00025

0.06

1.46728

1.88667

9

0.281999

35

0.281996

−14.4

1.2

2.26

606

1

GJ-50-17

0.0070

0.4

0.00025

0.06

1.46722

1.88668

9

0.282004

40

0.282002

−14.2

1.4

2.25

606

1

GJ-50-18

0.0069

0.3

0.00024

0.06

1.46725

1.88679

9

0.281987

35

0.281984

−14.8

1.2

2.28

606

1

GJ-50-19

0.0070

0.3

0.00025

0.04

1.46721

1.88672

9

0.282017

37

0.282014

−13.8

1.3

2.23

606

1

GJ-50-20

0.0070

0.3

0.00025

0.05

1.46727

1.88679

9

0.281973

39

0.281970

−15.3

1.4

2.31

606

1

GJ-50-21

0.0070

0.5

0.00025

0.05

1.46724

1.88670

9

0.281984

35

0.281981

−14.9

1.2

2.29

606

1

GJ-50-22

0.0070

0.4

0.00025

0.04

1.46727

1.88659

8

0.282006

38

0.282003

−14.1

1.3

2.25

606

1

GJ-50-23

0.0070

0.3

0.00025

0.06

1.46721

1.88676

8

0.282013

35

0.282010

−13.9

1.2

2.23

606

1

GJ-50-24

0.0071

0.4

0.00025

0.06

1.46726

1.88662

8

0.282007

36

0.282004

−14.1

1.3

2.25

606

1

GJ-50-25

0.0069

0.7

0.00024

0.06

1.46722

1.88669

8

0.281986

37

0.281984

−14.8

1.3

2.28

606

1

GJ-50-26

0.0071

0.4

0.00025

0.07

1.46725

1.88657

8

0.281997

39

0.281994

−14.5

1.4

2.26

606

1

GJ-50-27

0.0072

0.3

0.00026

0.04

1.46730

1.88664

9

0.282009

37

0.282006

−14.1

1.3

2.24

606

1

mean (n = 27)

0.0070

0.00025

1.46726

1.88673

0.282000

0.281997

−14.4

2 S.D.

0.0002

0.00001

0.00010

0.00018

0.000030

0.000030

1.1

zircon standard Plesovice

Pleso1

0.0042

0.3

0.00010

0.0

1.46724

1.88675

12

0.282457

37

0.282456

−5.2

1.3

1.55

337

1

Pleso2

0.0042

0.5

0.00010

0.0

1.46727

1.88676

11

0.282484

36

0.282483

−4.2

1.3

1.50

337

1

Pleso3

0.0043

0.5

0.00010

0.1

1.46718

1.88668

11

0.282462

35

0.282461

−5.0

1.2

1.54

337

1

Pleso4

0.0046

0.1

0.00011

0.1

1.46727

1.88675

24

0.282472

32

0.282471

−4.7

1.1

1.52

337

1

Pleso5

0.0033

0.2

0.00008

0.1

1.46719

1.88680

14

0.282468

34

0.282467

−4.8

1.2

1.53

337

1

Pleso6

0.0041

0.1

0.00009

0.0

1.46722

1.88690

15

0.282474

34

0.282473

−4.6

1.2

1.51

337

1

Pleso7

0.0056

0.7

0.00013

0.2

1.46720

1.88679

15

0.282466

34

0.282465

−4.9

1.2

1.53

337

1

Pleso8

0.0061

0.7

0.00015

0.2

1.46723

1.88679

13

0.282496

34

0.282495

−3.8

1.2

1.47

337

1

Pleso9

0.0062

0.9

0.00015

0.2

1.46727

1.88668

13

0.282485

37

0.282484

−4.2

1.3

1.49

337

1

Pleso10

0.0060

0.7

0.00015

0.2

1.46723

1.88685

13

0.282472

34

0.282472

−4.7

1.2

1.52

337

1

Pleso11

0.0044

0.2

0.00010

0.0

1.46729

1.88676

12

0.282512

37

0.282511

−3.2

1.3

1.44

337

1

Pleso12

0.0043

0.1

0.00010

0.0

1.46724

1.88676

12

0.282508

34

0.282507

−3.4

1.2

1.45

337

1

Pleso13

0.0043

0.2

0.00010

0.0

1.46730

1.88684

13

0.282487

36

0.282486

−4.1

1.3

1.49

337

1

Pleso14

0.0043

0.6

0.00010

0.1

1.46728

1.88692

12

0.282508

35

0.282507

−3.4

1.2

1.45

337

1

Pleso15

0.0041

0.7

0.00010

0.1

1.46732

1.88691

12

0.282518

36

0.282517

−3.0

1.3

1.43

337

1

Pleso16

0.0039

0.8

0.00009

0.2

1.46725

1.88672

12

0.282492

37

0.282492

−3.9

1.3

1.48

337

1

mean (n = 16)

0.0046

0.00011

1.46725

1.88679

0.282485

0.282484

−4.2

2 S.D.

0.0017

0.00004

0.00008

0.00015

0.000038

0.000038

1.3

zircon standard 91500

91500-1

0.0097

2

0.00032

0.3

1.46729

1.88677

13

0.282274

35

0.282268

5.6

1.2

1.53

1065

1

91500-2

0.0100

2

0.00033

0.5

1.46731

1.88683

12

0.282293

36

0.282287

6.3

1.3

1.49

1065

1

91500-3

0.0097

2

0.00033

0.4

1.46730

1.88688

12

0.282277

38

0.282271

5.7

1.4

1.52

1065

1

91500-4

0.0095

1

0.00032

0.3

1.46720

1.88686

7

0.282267

38

0.282261

5.3

1.4

1.54

1065

1

91500-5

0.0095

1

0.00032

0.1

1.46725

1.88654

8

0.282293

37

0.282287

6.3

1.3

1.49

1065

1

91500-6

0.0096

1

0.00031

0.2

1.46717

1.88661

8

0.282269

38

0.282262

5.4

1.4

1.54

1065

1

91500-7

0.0094

2

0.00031

0.3

1.46720

1.88655

7

0.282288

39

0.282282

6.1

1.4

1.50

1065

1

91500-8

0.0093

1

0.00030

0.1

1.46717

1.88642

8

0.282280

38

0.282274

5.8

1.4

1.52

1065

1

mean (n = 8)

0.0096

0.00032

1.46724

1.88668

0.282280

0.282274

5.8

2 S.D.

0.0005

0.00002

0.00012

0.00035

0.000021

0.000021

0.7

zircon standard Temora

Temora1

0.0221

2

0.00078

0.9

1.46725

1.88655

8

0.282643

39

0.282637

4.1

1.4

1.10

419

1

Temora2

0.0197

2

0.00069

0.2

1.46726

1.88674

9

0.282646

38

0.282641

4.2

1.3

1.09

419

1

Temora3

0.0292

3

0.00095

0.5

1.46728

1.88649

9

0.282648

40

0.282641

4.2

1.4

1.10

419

1

Temora4

0.0192

3

0.00068

1.1

1.46715

1.88651

5

0.282672

47

0.282667

5.2

1.6

1.04

419

1

Temora5

0.0232

10

0.00081

3.3

1.46712

1.88680

5

0.282691

48

0.282684

5.8

1.7

1.01

419

1

Temora6

0.0271

8

0.00094

2.3

1.46716

1.88669

5

0.282658

43

0.282650

4.6

1.5

1.08

419

1

Temora7

0.0334

5

0.00108

1.5

1.46728

1.88687

10

0.282650

37

0.282642

4.3

1.3

1.09

419

1

Temora8

0.0175

2

0.00058

0.9

1.46727

1.88666

11

0.282642

35

0.282637

4.1

1.2

1.10

419

1

mean (n = 8)

0.0239

0.00081

1.46722

1.88667

0.282656

0.282650

4.6

2 S.D.

0.0111

0.00033

0.00013

0.00027

0.000034

0.000034

1.2