| Reaction | Type | Enzyme | ΔE | Ea | Ec | t0 | nB |
| Catalyzed basic compound synthesis |
|
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|
|
|
|
| 2HCN + 2H2O + H2 → Gly(COOH−CH2NH2) + NH3 | 1 | GlyGly | 223 | 92.8 | 8.3 | 0.70 | 25 |
| 5HCN + 2H2O + 6H2 → Pro(C5H9NO2) + 4NH3 | 1 | ProPro | 741.7 | 256.1 | 0.53 | 0.47 | 53 |
| 3HCN + 2H2O + 2H2 + H2S → Cys(COOH−CHNH2−CH2−SH) + 2NH3 | 1 | GlyGlyGly | 1232.4 | 144.3 | 0.94 | 0.74 | 39 |
| 4HCN + H2O + H2 → Cyt(C4H5N3O) + NH3 | 1 | Pro | 403.5 | 140.2. | 17.5 | 0.76 | 28 |
| 5HCN + H2O → Gua(C5H5N5O) + H2 | 1 | GlyPro | 505. | 145.9 | 6.56 | 0.99 | 36 |
| 5HCN + H2O → Gua(C5H5N5O) + H2 | 1 | ProGly | 505. | 145.9 | 27.6 | 0.99 | 36 |
| FeS + H2S → FeS2 + H2 | 1 | Cys | 41. | 160.6 | 0.02 | 3.45 | 16 |
| Cyt(C4H5N3O3) + HCN + 6H2 → Pro(C5H9NO2) + H2O + 2NH3 | 1 |
| 582.9 | 21.7 |
| 1.02 | 16 |
| 3HCN + 2H2O + 4H2 + H3PO4 → Glyc1ph + 3NH3 | 1 | GlyGlyGly | 395.5 | 139.5 | 6.6 | 0.99 | 27 |
| simple PNA polymerization |
|
|
|
|
|
|
|
| Gly + Gly + GuaGua → GlyGuaGlyGua(6H−) + 2H2O | 5 |
| −94.2 | 16.4 |
| 1.53 | 53 |
| Gly + Gly + Gly + Gua3 → GlyGua3(12H−) + 3H2O | 5 |
| −109.8 | 16.5 |
| 1.60 | 81 |
| Pro + Pro + CytCyt → ProCytProCyt(9H−) + 2H2O | 5 |
| 692.8 | 5.9 |
| 2.26 | 63 |
| Gly + Pro + GuaCyt → GlyGuaProCyt(13H−) + 2H2O | 5 |
| −146.5 | 15.1 |
| 1.89 | 61 |
| Gly + Pro + CytGua → ProCytGlyGua(13H−) + 2H2O | 5 |
| −146.5 | 15.1 |
| 1.89 | 61 |
| Gly + Pro + GuaCyt → GlyCytProGua(13H−) + 2H2O | 5 |
| −146.5 | 15.1 |
| 1.89 | 61 |
| PNB polymerization |
|
|
|
|
|
|
|
| Cyt + Cyt → CytCyt(3H−) | 2 |
| 491. | 5.0 |
| 1.31 | 26 |
| Gua + Gua → GuaGua(3H−) | 2 |
| 705.3 | 2.9 |
| 1.14 | 34 |
| Gua + Gua + Gua → Gua3(6H−) | 2 |
| 1089.5 | 3.7 |
| 1.14 | 51 |
| Gua + Cyt → GuaCyt(6H−) | 2 |
| 661.2 | 6.9 |
| 1.22 | 30 |
| Cyt + Gua → CytGua(6H−) | 2 |
| 661.2 | 6.9 |
| 1.22 | 30 |
| peptide formation |
|
|
|
|
|
|
|
| GlyGuaGlyGua + 2H2O → GuaGua(3H−) + GlyGly + H2O | 6 |
| 661.6 | 12.5 |
| 2.46 | 58 |
| ProCytProCyt + 2H2O → CytCyt(3H−) + ProPro + H2O | 6 |
| 566.1 | 7.0 |
| 3.61 | 62 |
| GlyGuaProCyt + 2H2O → GuaCyt(6H−) + GlyPro + H2O | 6 |
| 308.6 | 9.2 |
| 3.05 | 58 |
| ProCytGlyGua + 2H2O → CytGua(6H−) + ProGly + H2O | 6 |
| 1008. | 3.0 |
| 3.05 | 58 |
| GlyGuaGlyGuaGlyGua + 3H2O → GuaGuaGua(8H−) + GlyGlyGly + 2H2O | 6 |
| 640.6 | 8.1 |
| 1.13 | 90 |
| multiple PNA polymerization |
|
|
|
|
|
|
|
| GlyGua + GlyGua → GlyGuaGlyGua(6H−) | 4 |
| 126. | 3.0 |
| 1.66 | 48 |
| 3GlyGua → (GlyGua)3(12H−) | 4 |
| 252. | 3.9 |
| 1.66 | 72 |
| ProCyt + ProCyt → ProCytProCyt(9H−) | 4 |
| 189. | 4.3 |
| 1.66 | 48 |
| GlyGua + ProCyt → GlyGuaProCyt(13H−) | 4 |
| 273. | 5.80 |
| 1.66 | 48 |
| GlyGua + ProCyt → ProCytGlyGua(13H−) | 4 |
| 273. | 5.80 |
| 1.66 | 48 |
| PNA building |
|
|
|
|
|
|
|
| Gly + Gua → GlyGua + H2O | 3 |
| 339.4 | 14.6 |
| 1.38 | 26 |
| Gly + Cyt → GlyCyt + H2O | 3 |
| 1156. | 17.2 |
| 1.47 | 22 |
| Pro + Cyt → ProCyt + H2O | 3 |
| −44.3 | 12.6 |
| 1.79 | 30 |
| Pro + Gua → ProGua + H2O | 3 |
| 62.8 | 11.1 |
| 1.67 | 34 |
| Leu + Gua → LeuGua + H2O | 3 |
| 339. | 10. |
| 1.79 | 38 |
| His + Cyt → HisCyt + H2O | 3 |
| 109.4 | 11.9 |
| 1.70 | 32 |
| diverse synthesis and energy cycles |
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|
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|
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|
| CO2 + NH3 + H2 → HCN + 2H2O | 7 |
| −90.9 | 74.2 |
| 3.45 | 6 |
| CO2 + NH3 + SH2 → HCN + 2H2O + S | 7 |
| −111.5 | 6.5 |
| 3.45 | 7 |
| FeS + H2S → FeS2 + H2 | 7 |
| 41. | 160.6 |
| 3.45 | 3 |
| CO2 + H2 → CO + H2O | 7 |
| 90.1 | 115.8 |
| 0.23 | 3 |
| CO + H2O → HCOOH | 7 |
| 548.8 | 73.3 |
| 0.20 | 3 |
| Gly + H2O → Gle(HCO−HCOH−H2COH) + NH3 | 7 |
| 346.2 |
|
| 1.62 | 9 |
| basic compounds decay by hydrolysis C=O |
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|
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|
|
|
| Gly(COOH−CH2NH2) + H2O → OH−CH2NH2 + HCOOH | 8 |
| −335.9 | 9.0 |
| 1.66 | 11 |
| Cys(COOH−CHNH2−CH2−SH) + H2O → OH−CHNH2−CH2−SH + HCOOH | 8 |
| −157 | 6.6 |
| 5.29 | 15 |
| Pro(COOH−ring(−NH−)) + H2O → OH−ring() + HCOOH | 8 |
| −612.4 | 5.2 |
| 2.45 | 19 |
| Cyt(ring(−C=O−)) + H2O → ring() + HCOOH | 8 |
| −89.4 | 20.5 |
| 1.30 | 15 |
| Gua(ring(−C=O−ring(−NH−CH−N−))) + H2O → ring(−ring(−NH−CH−N−)) + HCOOH | 8 |
| −15.1 | 5.2 |
| 1.14 | 19 |
| direct peptide polymerization |
|
|
|
|
|
|
|
| Gly + Gly → GlyGly + H2O | 9 |
| −117.7 | 64.8 |
| 1.66 | 18 |
| Gly + Gly + Gly → GlyGlyGly + 2H2O | 9 |
| −99.5 | 83.8 |
| 1.66 | 27 |
| Pro + Pro → ProPro + H2O | 9 |
| −1097.7 | 27.9 |
| 2.45 | 34 |
| Gly + Pro → GlyPro + H2O | 9 |
| −258. | 43.7 |
| 2.02 | 26 |
| Gly + Pro → ProGly + H2O | 9 |
| −258. | 43.7 |
| 2.02 | 26 |
| GlyGly + Gly → GlyGly + H2O | 9 |
| +18.2 | 48. |
| 1.77 | 24 |