[Cu2 (H2L)2(SO4)(H2O)2]

Endo

366.40

12.36

2.43

1.35

−0.13

−46.58

13.03

34.1˚C - 200˚C

11.22

11.42

Dehydration of two molecules coordination water and CO

Exo

655.50

412.17

2.35

1.63

−0.10

−63.69

267.20

200˚C - 428˚C

66.29

65.94

Elimination of the rest of complex and formation of 2Cu

[Zn(H2L)2 (H2O)2]4H2O

Endo

403.50

28.84

1.30

1.84

−0.12

−49.28

21.53

77.2˚C - 196.6˚C

11.58

11.64

Loss of 3H2O and H2

Endo

535.30

162.52

1.21

2.03

−0.11

−57.67

91.76

196.6˚C - 360.8˚C

12.00

11.94

Dehydration of 3H2O and 2H2

Exo

615.70

28.51

1.35

1.70

−0.12

−75.19

14.13

360.8˚C - 500.8˚C

38.07

38.00

Elimination of C2N2O2 and C2N2O3

Exo

774.80

153.50

1.53

1.84

−0.11

−83.19

66.23

500.8˚C - 599.1˚C

9.10

8.85

Elimination of CO2 and formation of ZnO and 5C

[Cd(H2L)2(H2O)2] H2O

Endo

381.10

16.90

1.41

1.66

−0.13

−48.10

13.98

44.8˚C - 108.8˚C

11.34

11.27

Dehydration of water molecules from outer and coordination sphere

Endo

533.10

74.01

1.41

1.87

−0.11

−60.66

44.52

108.8˚C - 280.3˚C

16.80

16.86

Elimination of CO and C2N2

Endo

612

337.30

1.00

2.21

−0.10

−62.85

147.15

280.3˚C - 400.7˚C

32.76

32.95

Elimination of CH4 and 5CO

Endo

646.10

373.06

1.56

1.87

−0.10

−64.15

210.18

Exo

804.70

164.07

1.01

2.15

−0.11

−87.90

51.00

400.7˚C - 540.9˚C

12.18

12.02

Elimination of NO, CH2N and formation of CdO

[Hg (H3L)2Cl2(H2O)2]

Endo

363.80

15.61

1.55

1.61

−0.13

−46.00

14.20

59.8˚C - 128.1˚C

8.71

8.33

Loss of 3H2O

Exo

629.40

18.21

1.37

1.50

−0.13

−79.17

8.90

128.1˚C - 462.6˚C

89.32

89.63

Elimination of the rest of complex and formation of carbon residue

[Co2Ni(HL)2 (OH)2(H2O)4]∙H2O

Exo

588.46

511.06

1.09

2.14

−0.10

−57.65

270.33

60.4˚C - 335.9˚C

19.20

18.72

Loss of 5H2O + HCN

Exo

617

298.89

1.20

2.06

−0.10

−63.26

148.99

335.9˚C - 488.3˚C

43.83

44.54

Elimination of the rest of complex and formation of 2CoO + NiO

Endo

628

363.11

1.17

2.29

−0.10

−63.38

177.55