Group

Complexes

Structure electronic of Ru

Valence electrons

Ru(II)

α-RuCl₂(Azpy)₂

Structure

(4d_x²−y²)^1.70

(4d_yz)^1.48

(4d_z²)^1.44

(4d_xz)^1.25

(4d_xy)^1.25

(5s)^0.27

7.35

Energy

−0.23

−0.23

−0.22

−0.21

−0.21

0.29

$\text{Fac-Ru}{\left(\text{Azpy}\right)}_3^{2+}$

Structure

(4d_x²−y²)^1.41

(4d_yz)^1.19

(4d_z²)^1.91

(4d_xz)^1.19

(4d_xy)^1.41

(5s)^0.23

(5p_x)^0.15

(5p_y)^0.15

(5p_z)^0.12

7.78

Energy

−0.44

−0.41

−0.45

−0.41

−0.44

0.03

0.03

0.03

−0.01

$\text{Mer-Ru}{\left(\text{Azpy}\right)}_3^{2+}$

Structure

(4d_x²−y²)^1.24

(4d_yz)^1.08

(4d_z²)^1.47

(4d_xz)^1.67

(4d_xy)^1.03

(5s)^0.23

(5p_x)^0.16

(5p_y)^0.12

(5p_z)^0.14

7.78

Energy

−0.42

−0.42

−0.43

−0.45

−0.41

−0.03

0.01

0

0.02

$\text{Ru}{\left(\text{Bipy}\right)}_3^{2+}$

Structure

(4d_x²−y²)^1.44

(4d_yz)^1.18

(4d_z²)^1.92

(4d_xz)^1.18

(4d_xy)^1.44

(5s)^0.19

(5p_x)^0.14

(5p_y)^0.14

(5p_z)^0.11

7.34

Energy

−0.40

−0.38

−0.42

−0.38

−0.44

0.10

0.13

0.13

0.08

Ru(III)

NAMI

Structure

(4d_x²−y²)^0.97

(4d_yz)^1.23

(4d_z²)^0.95

(4d_xz)^1.95

(4d_xy)^1.95

(5s)^0.29

7.23

Energy

−0.05

−0.08

−0.07

−0.10

−0.10

0.42

NAMI-A

Structure

(4d_x²−y²)^0.98

(4d_yz)^1.03

(4d_z²)^1.17

(4d_xz)^1.92

(4d_xy)^1.95

(5s)^0.32

7.4

Energy

−0.10

−0.11

−0.11

−0.14

−0.14

0.28

RuCl₃Terpy

Structure

(4d_x²−y²)^0.94

(4d_yz)^1.2

(4d_z²)^0.91

(4d_xz)^1.91

(4d_xy)^1.92

(5s)^0.28

(5p_x)^0.29

(5p_y)^0.19

(5p_z)^0.24

7.89

Energy

−0.20

−0.25

−0.22

−0.33

−0.33

0.40

0.39

0.28

0.38

RuCl₃(H₂O)Gly

Structure

(4d_x²−y²)^0.92

(4d_yz)^1.72

(4d_z²)^1.25

(4d_xz)^1.06

(4d_xy)^1.75

(5s)^0.27

(5p_x)^0.22

(5p_y)^0.22

(5p_z)^0.20

7.66

Energy

−0.24

−0.34

−0.28

−0.25

−0.35

0.23

0.33

0.31

0.30

RuCl₃(H₂O)₃

Structure

(4d_x²−y²)^0.77

(4d_yz)^1.21

(4d_z²)^0.83

(4d_xz)^1.98

(4d_xy)^1.98

(5s)^0.27

7.05

Energy

−0.23

−0.27

−0.25

−0.29

−0.29

0.23