(S) - (−)- carvone salicylhydrazone

(R) - (+)- carvone salicylhydrazone

δ

(ppm)

EXP

(ppm) [9]

6-311G (d, p)

δ

(ppm)

EXP

(ppm) [9]

6-311G (d, p)

B3LYP

M05-2X

B3LYP

M05-2X

C¹⁸

20.45

18.78

08.67

C²⁰

162.85

161.92

169.85

C²²

148.00

19.87

09.23

C²⁷

152.78

154.54

159.99

C⁷

29.10

26.68

17.79

C²

20.44

38.12

169.85

C³

148.52

132.40

166.87

C³

20.45

34.54

24.41

C²

147.17

139.01

30.29

C³⁵

31.73

68.80

59.20

C¹

107.20

47.00

158.39

C³²

29.47

136.89

145.56

C²⁶

163.15

148.04

35.43

C²⁴

148.52

150.17

158.06

C²¹

36.16

49.83

38.58

C⁷

40.10

166.00

159.99

C²⁰

31.75

54.46

48.46

C⁸

16.77

20.95

13.43

C²³

40.10

60.16

53.01

C⁹

33.16

161.60

39.73

C²⁵

33.16

64.95

55.63

C¹⁰

40.10

48.40

44.92

C⁸

40.70

70.11

58.41

C¹¹

33.87

50.10

40.28

-

-

-

-

C¹²

32.28

20.66

12.91

-

-

-

-

C¹³

119.59

60.46

51.87

-

-

-

-

C¹⁵

48.67

65.87

58.30

-

-

-

-

C¹⁶

53.99

48.22

37.19

-

-

-

-

C³⁴

17.68

20.63

09.62