Complexes

Structure electronic of Ru

valence electrons

α-RuCl₂(Dazpy)₂

Structure

(4d_yz)^1.89

(4d_xy)^1.68

(4d_z²)^1.37

(4d_xz)^0.95

(4d_{x² − y²})^1.19

(5s)^0.27

7.35

Energy

−0.221

−0.215

−0.202

−0.199

−0.187

0.208

β-RuCl₂(Dazpy)₂

Structure

(4d_xy)^1.94

(4d_xz)^1.70

(4d_z²)^1.36

(4d_yz)^1.09

(4d_{x² − y²})^0.99

(5s)^0.28

7.36

Energy

−0.237

−0.224

−0.212

−0.204

−0.186

0.231

γ-RuCl₂(Dazpy)₂

Structure

(4d_{x² − y²})^1.67

(4d_z²)^1.69

(4d_yz)^1.50

(4d_xy)^1.09

(4d_xz)^1.14

(5s)^0.28

7.37

Energy

−0.227

−0.212

−0.206

−0.199

−0.188

0.237

δ-RuCl₂(Dazpy)₂

Structure

(4d_yz)^1.93

(4d_xy)^1.81

(4d_xz)^1.57

(4d_z²)^0.89

(4d_{x² − y²})^0.91

(5s)^0.27

7.38

Energy

−0.222

−0.217

−0.215

−0.181

−0.170

0.217

ε-RuCl₂(Dazpy)₂

Structure

(4d_{x² − y²})^1.67

(4d_xz)^1.38

(4d_z²)^1.63

(4d_xy)^1.10

(4d_yz)^1.31

(5s)^0.27

7.36

Energy

−0.222

−0.213

−0.212

−0.193

−0.192

0.221

RuCl₃.3H₂O

Structure

(4d_xy)^1.99

(4d_yz)^1.99

(4d_xz)^1.21

(4d_z²)^0.83

(4d_{x² − y²})^0.76

(5s)^0.28

7.06

Energy

−0.290

−0.288

−0.263

−0.249

−0.232

0.235

Ru atom

Structure

(4d_xy)²

(4d_xz)²

(4d_yz)²

(4d_z²)^1.51

(5s)^0.49

(4d_{x² − y²})⁰

8

Energy

−0.200

−0.181

−0.180

−0.148

−0.119

−0.100