Complex | Stage | Method | Parameter | r | ||||
E (J・mol−1) | A (s−1) | ΔS (J・mol−1・K−1) | ΔH (J・mol−1) | ΔG (J・mol−1) | ||||
(III) | 1st | CR HM | 3.23 × 105 3.51 × 105 | 1.82 × 1033 2.96 × 1036 | 3.88 × 102 4.49 × 102 | 3.19 × 105 3.47 × 105 | 1.31 × 105 1.29 × 105 | 0.9984 0.9989 |
(IIIa) | 1st | CR HM | 4.56 × 104 5.49 × 104 | 1.31 × 102 2.02 × 103 | −2.09 × 102 −1.86 × 102 | 4.13 × 104 5.05 × 104 | 1.50 × 105 1.47 × 105 | 0.9988 0.9953 |
(IIIb) | 3st | CR HM | 1.67 × 105 2.13 × 105 | 5.30 × 105 5.28 × 107 | −1.46 × 102 −1.08 × 102 | 1.57 × 105 2.04 × 105 | 3.20 × 105 3.24 × 105 | 0.9993 0.9985 |
(IIIc) | 1st | CR HM | 1.95 × 105 2.06 × 105 | 5.85 × 1018 1.77 × 1020 | 1.10 × 102 1.39 × 102 | 1.91 × 105 2.02 × 105 | 1.37 × 105 1.34 × 105 | 0.9992 0.9974 |
(IIId) | 1st | CR HM | 8.08 × 104 9.84 × 104 | 3.72 × 106 2.60 × 108 | −1.23 × 102 −8.81 × 101 | 7.66 × 104 9.43 × 104 | 1.38 × 105 1. 38 × 105 | 0.9984 0.9984 |