Compound

steps

Temperature

range (˚C)

TG weight loss (%)

Assignment

Tmax˚C

Calc.

Found

(III)

1

25 - 234

35.80

36.00

2(HCN), 2N2 and S2 fragments

211

276

503

2

234 - 334

32.30

32.10

O2 and C4H6

3

More than 334

31.70

31.90

C12H10

(IIIa)

1

25 - 332

32.00

31.90

6 water and 2(HCN) and N2H2

246

473

704

828

2

332 - 550

16.80

16.90

S2, O2 and C2H2

3

550 - 895

24.80

24.60

C8H6

4

More than 895

26.80

26.60

3/2C2 and Co2 metal

(IIIb)

1

25 - 465

17.80

17.80

10water

208

540

840

977

2

465 - 700

14.80

15.00

2(HCN), 2N2 and 2(CH2)

3

700 - 910

34.70

33.90

2(C6H4) and 2S2

4, 5

910 - 1000

32.60

33.27

Carbon and 4(CuO)

(IIIc)

1

25 - 237

19.90

20.00

two water and two acetone molecules

221

348

560

2

237 - 365

25.38

25.30

2(HCN) 2(HNCO) 2CH and N2 fragment

3

More than 365

54.66

54.70

S2, (C6H4) and Zn2

(IIId)

1

25 - 239

13.10

13.00

6 water molecules

226

302

530

572

2

239 - 321

13.30

12.70

2HCN and 2N2

3,4

321 - 700

20.20

20.80

S2 and O2 fragments

5

More than 700

53.40

53.50

residue metal of Sn2 and contaminated of (C16H12) fragments