Compound | Steps | Temperature ring (˚C) | TG weight loss (%) | Assignments | Tmax/˚C | |
Calc. | Found | |||||
(II) | 1 | 25 - 245 | 39.00 | 39.10 | 2(HNCO), 2H2S and 2(NH) fragments | 212 278 524 |
2 | 245 - 345 | 32.50 | 32.80 | 2(HCN), (C2H2) | ||
3 | More than 345 | 26.80 | 27.50 | (C17H2) residual | ||
(IIa) | 1 | 25 - 188 | 4.94 | 5.20 | 2 water | 242 477 854 959 |
2 | 188 - 448 | 33.50 | 33.10 | 6 water molecules, 2N2, 2(HCN), and C2H2 fragments | ||
3 | 448 - 760 | 22.90 | 23.40 | S2 and O2 molecules | ||
4 | 760 - 885 | 22.50 | 21.80 | CH4 and C12H4 fragments | ||
5 | More than 885 | 16.50 | 17.30 | Co2 molecule is cobalt residue | ||
(IIb)
| 1,2 | 25 - 245 | 15.40 | 16.40 | 6 water | 181 277 506 680 974 |
3 | 245 - 475 | 20.50 | 20.60 | N2, 2(HCN), N2H2, and O2 | ||
4 | 475 - 765 | 42.50 | 42.40 | C13H8, S2) fragments | ||
5 | More than 765 | 21.50 | 20.60 | Cu2 metal residual | ||
(IIc) | 1 | 25 - 224 | 15.300 | 15.50 | 6 water molecules | 219 309 |
2 | 224 - 338 | 26.90 | 26.50 | 2N2, S2, 1/2O2 and 2(HCN) fragment | ||
3 | 338 - 643 | 18.20 | 18.60 | 1/2O2, CH4 and C2H2 molecules | ||
4 | More than 643 | 39.50 | 39.40 | residue metal of Zn2 and C12H4 fragment | ||
(IId) | 1,2 | 25 - 322 | 25.20 | 24.70 | 8 H2O, HNCO and HCN molecules | 229 301 518 |
3 | 322 - 506 | 8.80 | 9.30 | 1/2S2 and HNCO | ||
4 | 506 - 589 | 9.10 | 9.56 | NH3, N2 and 1/2S2 molecules | ||
5 | More than 589 | 56.80 | 56.44 | C14H6 and Sn2 the residual metal |