Compounds

λmax nm (cm−1)

π-π*, C=S

n-π*, C=S

d-d transition

(I)

256, (39060)

314, (31850)

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(Ia)

260, (38460)

313, (31950)

494, (20240)

559, (17889)

578, (17300)

(Ib)

268, (37300)

310, (32260)

486, (20600)

540, (18520)

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(Ic)

265, (37740)

317, (31550)

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(Id)

266, (37600)

324, (30860)

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(II)

287, (34840)

344, (29070)

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(IIa)

288, (34720)

342, (29240)

462, (21650)

485, (20620)

522, (19160)

(IIb)

308, (32470)

358, (27930)

466, (21460)

493, (20280)

524, (19080)

(IIc)

284, (35210)

344, (29070)

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(IId)

288, (34720)

330, (30300)

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(III)

264, (37880)

328, (30490)

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(IIIa)

296, (33780)

356, (28090)

540, (18520)

600, (16670)

622, (16080)

(IIIb)

256, (39060)

320, (31250)

543, (18420)

610, (16390)

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(IIIc)

280, (35710)

332, (30120)

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(IIId)

260, (38460)

304, (32890)

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