Compound | DTA Peak Temp. (˚C) | Thermogravimetry | Possible Intermediates/End Products | ||
Temp. Range/˚C | Mass Loss (%) | ||||
Obsd. | Calcd. | ||||
H2Agun∙CO3 |
| 90 - 180 | 69.00 | 69.12 | Formation of NH=C=NH |
|
| 180 - 600 | 100 | 100 | Complete Decomposition |
La2(tdp)3(Agun)2∙2H2O |
| 80 - 200 | 3.60 | 4.04 | La2(tdp)3(Agun)2 |
|
| 200 - 350 | 18.70 | 20.35 | La2(tdp)3 |
|
| 350 - 750 | 62.00 | 62.45 | La2S3 |
Pr2(tdp)3(Agun)2∙2H2O |
| 90 - 250 | 3.70 | 4.00 | Pr2(tdp)3(Agun)2 |
|
| 250 - 400 | 19.30 | 20.04 | Pr2(tdp)3 |
|
| 400 - 750 | 53.40 | 60.79 | Pr2S3 |
Nd2(tdp)3(Agun)2∙2H2O |
| 90 - 250 | 3.60 | 4.00 | Nd2(tdp)3(Agun)2 |
|
| 250 - 400 | 18.50 | 19.50 | Nd2(tdp)3 |
|
| 400 - 750 | 54.50 | 61.77 | Nd2S3 |
Sm2(tdp)3(Agun)2∙2H2O |
| 90 - 250 | 3.60 | 4.00 | Sm2(tdp)3(Agun)2 |
|
| 250 - 400 | 16.50 | 17.50 | Sm2(tdp)3 |
|
| 400 - 750 | 55.60 | 61.77 | Sm2S3 |