T

(K)

Equations

R²

K_ads.10³

(M⁻¹)

$\Delta G_{ads}^0$

(kJ∙mol⁻¹)

$\Delta G_{ads}^0$

(kJ∙mol⁻¹)

$\Delta S_{ads}^0$

(J∙mol⁻¹∙K⁻¹)

298

$\frac{C_{inh}}{\theta }=0.876C_{inh}+0.0808$

0.998

12.36

−33.279

16.318

166.5

303

$\frac{C_{inh}}{\theta }=0.8915C_{inh}+0.0687$

0.991

14.556

−34.249

308

$\frac{C_{inh}}{\theta }=0.8537C_{inh}+0.0661$

0.997

15.128

−34.913

313

$\frac{C_{inh}}{\theta }=0.8404C_{inh}+0.0618$

0.99

16.181

−35.655

318

$\frac{C_{inh}}{\theta }=0.8403C_{inh}+0.0526$

0.993

19.011

−36.650

323

$\frac{C_{inh}}{\theta }=0.8286C_{inh}+0.0472$

0.994

21.186

−37.517