Imide | Oxirane | Rate constants k3/2・105 [mol−1/2∙s−1∙dm3/2] at temperature [K] | |||||
298 | 303 | 308 | 313 | 318 | 323 | ||
SI | EO | 1.21 ± 0.02 | 1.73 ± 0.06 | 2.69 ± 0.07 | 4.37 ± 0.20 |
|
|
PO |
|
| 1.28 ± 0.05 | 1.76 ± 0.10 | 3.10 ± 0.18 | 4.85 ± 0.28 | |
PI | EO | 1.25 ± 0.03 | 1.95 ± 0.02 | 3.17 ± 0.17 | 4.52 ± 0.20 |
|
|
PO |
|
| 1.53 ± 0.13 | 2.18 ± 0.12 | 3.15 ± 0.11 | 4.53 ± 0.35 | |
GI | EO | 1.94 ± 0.33 | 3.09 ± 0.36 | 4.07 ± 0.35 | 6.17 ± 0.22 |
|
|
PO |
|
| 1.77 ± 0.22 | 2.18 ± 0.13 | 3.88 ± 0.30 | 5.47 ± 0.22 |