c0 SI = 4.0012 mol/dm3

c0 EO = 0.2508 = mol/dm3

cNaOH = 0.2014 mol/dm3

Reaction time [min]

Relative concentration of EO (b)

k1・105 [s−1]

130

0.8075

2.74

180

0.7487

2.68

230

0.6985

2.60

260

0.6625

2.64

320

0.6047

2.62

390

0.5468

2.58

450

0.4929

2.62

490

0.4508

2.71

580

0.4060

2.59

660

0.3499

2.65

750

0.3021

2.66

890

0.2508

2.59

10,300

0.2005

2.60

k1/2 av・105 [s−1]

2.64 ± 0.05