Entry
Metal catalyst precursor [mol %]
Yield
[%]b
Ee
[%]c
1
[Ir(OMe)(cod)]2 (3) [3]
86
92
2
3 [2.5]
72
85
3
Ir(acac)(cod) (28) [6]
96
80
4
28 [5]
90
85
5
[IrCl(cod)]2 (5) [3]
97
92
6
5 [2.5]
99
93
7
[IrCl(cyclooctene)2]2 (29) [2.5]
20
76
8
[Ir(cod)2]+{B [3,5-(CF3)2C6H3]4}⁻ (30) [5]
17
86
9
[IrCp*Cl2]2 (31) [2.5]
<5
-
10
[RhCl(cod)]2 (32) [2.5]
<5
-
11
[Rh(cod)2]+BF4⁻ (33) [5]
11
15
12
PdCl2(cod) (34) [5]
18
<1
13
PtCl2(cod) (35) [5]
<1
-
14
[RuCl2(cod)]n (36) [5]
<5
-
15
[CuCl(cod)]2 (37) [5]
<1
-