N

Alkane

k_exp. × 10¹²

(cm³∙mol⁻¹∙s⁻¹)

−logk_exp.

|E_orb|

(kJ·mol⁻¹)

−logk_calc.

1

Ethane

0.222

12.65

893.58

12.66

2

Propane

1.12

11.95

873.56

11.95

3

Butane

2.10

11.68

863.34

11.68

4

Pentane

5.30

11.28

845.16

11.27

5

Hexane

5.91

11.22

841.27

11.19

6

Heptane

7.26

11.14

837.02

11.11

7

Octane

8.24

11.08

835.47

11.09

8

Nonane

9.36

11.03

833.73

11.05

9

Decane

9.90

11.00

833.00

11.04