N. | Nominal composition Ho, Al, Si/at % | Phases crystal structure | EDXS results Ho, Al, Si/at % | Lattice parameters/nm | |||
a | b | c | β/˚ | ||||
1 | 5.0, 38.0, 57.0 | Si cF8-Cdiam | 0.0, 0.0, 100.0 | 0.5428 (1) |
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Al cF4-Cu | 0.0, 100.0, 0.0 | 0.4045 (1) |
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τ2mS14-Y2Al3Si2 | 29.0, 45.0, 26.0 | 1.0083 (2) | 0.4013 (1) | 0.6560 (8) | 100.82 | ||
2 | 16.5, 75.5, 8.0 | Al cF4-Cu | 0.0, 100.0, 0.0 | 0.4047 (1) |
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τ2mS14-Y2Al3Si2 | 30.0, 45.5, 24.5 | 1.0091 (9) | 0.4015 (5) | 0.6572 (9) | 100.78 | ||
HoAl3−xSixhR60-HoAl3 | 26.0, 67.0, 7.0 | 0.6100 (1) | 0.6100 (1) | 3.4961 (9) |
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3 | 18.5, 14.0, 67.5 | Si cF8-Cdiam | 0.0, 0.0, 100.0 | 0.5426 (3) |
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τ2mS14-Y2Al3Si2 | 29.5, 44.0, 26.5 | 1.0093 (5) | 0.4012 (1) | 0.6563 (1) | 100.82 | ||
HoSi2−aoI12-GdSi2 | 36.0, 0.0, 64.0 | 0.3915 (2) | 0.4015 (1) | 1.3371 (9) |
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4 | 25.0, 34.0, 41.0 | Si cF8-Cdiam | 0.0, 0.0, 100.0 | 0.5424 (4) |
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τ2mS14-Y2Al3Si2 | 31.0, 43.0, 26.0 | 1.0090 (7) | 0.4011 (3) | 0.6561 (5) | 100.94 | ||
5 | 40.5, 51.0, 8.5 | Ho Al(2−x)SixcF24-MgCu2 | 33.0, 64.0, 3.0 | 0.7825 (2) |
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HoAl1−xSixoP16-AlEr | 48.0, 40.0, 12.0 | 0.5900 (2) | 1.1401 (9) | 0.5578 (3) |
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6 | 54.0, 24.0, 22.0 | Ho5Si3hP16-Mn5Si3 | 66.5, 0.0, 33.5 | 0.8371 (9) | 0.8371 (9) | 0.6276 (9) |
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HoAl1−xSixoP16-AlEr | 52.0, 33.0, 15.0 | 0.5739 (4) | 1.1250 (5) | 0.5691 (8) |
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7 | 39.0, 37.0, 24.0 | Ho5Si4oP36-Ge4Sm5 | 56.0, 0.0, 44.0 | 0.7335 (4) | 1.4406 (5) | 0.7614 (2) |
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HoAl2−xSixcF24-MgCu2 | 33.0, 64.5, 2.5 | 0.7800 (3) |
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τ4oI10 W2CoB2 | 43.0, 25.0, 32.0 | 0.4005 (1) | 0.5903 (3) | 0.8528 (1) |
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8 | 32.0, 55.0, 13.0 | τ4oI10 W2CoB2 | 42.5, 26.0, 31.5 | 0.4143 (6) | 0.5712 (4) | 0.8519 (4) |
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HoAl2−xSixcF24-MgCu2 | 34.0, 63.0, 3.0 | 0.7796 (3) |
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HoAl3−xSix hR60-HoAl3 | 26.5, 68.5, 5.0 | 0.6011 (6) | 0.6011 (6) | 3.5550 (5) |
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9 | 57.0, 3.0, 40.0 | Ho5Si3hP16-Mn5Si3 | 67.5, 0.0, 32.5 | 0.8341 (2) | 0.8341 (2) | 0.6215 (5) |
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Ho5AlxSi(4−x)oP36-Ge4Sm5 | 55.0, 4.0, 41.0 | 0.7315 (6) | 1.4429 (6) | 0.7610 (2) |
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10 | 57.5, 12.5, 30.0 | Ho5Si3hP16-Mn5Si3 | 65.0, 0.0, 35.0 | 0.8329 (3) | 0.8329 (3) | 0.6217 (5) |
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Ho5Si(4−x)Alx oP36-Ge4Sm5 | 53.5, 6.0, 40.5 | 0.7321 (5) | 1.4439 (1) | 0.7616 (9) |
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HoAl1−xSix oP16-AlEr | 45.0, 41.0, 14.0 | 0.5752 (4) | 1.1167 (2) | 0.5579 (6) |
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11 | 56.0, 36.0, 8.0 | Ho5AlxSi3−xhP16-Mn5Si3 | 65.5, 11.5, 23.0 | 0.8354 (2) | 0.8354 (2) | 0.6262 (5) |
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HoAloP16-AlEr | 50.0, 50.0, 0.0 | 0.5803 (9) | 1.1288 (8) | 0.5584 (6) |
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τ5tI80-Tb6Al3Si | 55.0, 35.0, 10.0 | 1.1392 (3) | 1.1392 (3) | 1.4981 (2) |
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12 | 76.0, 6.0, 18.0 | Ho5AlxSi3−xhP16-Mn5Si3 | 67.5, 8.0, 26.5 | 0.8355 (3) | 0.8355 (3) | 0.6266 (5) |
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(Ho) hP2-Mg | 100.0, 0.0, 0.0 | 0.3618 (5) | 0.3618 (5) | 0.5650 (3) |
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13 | 75.5, 15.0, 9.5 | (Ho) hP2-Mg | 100.0, 0.0, 0.0 | 0.3614 (4) | 0.3614 (4) | 0.5644 (7) |
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Ho2Al(1−x)SixoP12-Co2Si | 66.5, 19.0, 14.5 | 0.6537 (2) | 0.5052 (1) | 0.9330 (2) |
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14 | 46.5, 39.0, 14.5 | HoAl1−xSixoP16-AlEr | 52.5, 15.0, 32.5 | 0.5801 (5) | 1.1342 (2) | 0.5641 (4) |
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Ho5AlxSi(4−x)oP36-Ge4Sm5 | 55.0, 36.5, 8.5 | 0.7336 (9) | 1.4419 (8) | 0.7597 (8) |
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HoAl(2−x)SixcF24-MgCu2 | 36.5, 60.5, 3.0 | 0.7815 (1) |
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15 | 54.5, 8.5, 37.5 | Ho5AlxSi(4−x)oP36-Ge4Sm5 | 55.0, 4.0, 41.0 | 0.7310 (9) | 1.4450 (9) | 0.7643 (7) |
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16 | 48.5, 8.5, 45.5 | Ho5Si4oP36-Ge4Sm5 | 55.0, 0.0, 45.0 | 0.7338 (7) | 1.4403 (9) | 0.7611 (9) |
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τ4oI10-W2CoB2 | 42.5, 19.0, 38.5 | 0.4022 (4) | 0.5739 (3) | 0.8583 (6) |
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HoSi2−bhP3-AlB2 | 38.0, 6.0, 56.0 | 0.3804 (1) | 0.3804 (1) | 0.4098 (2) |
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17 | 37.0, 23.0, 40.0 | τ4.oI10-W2CoB2 | 41.0, 18.0, 41.0 | 0.4017 (2) | 0.5740 (2) | 0.8577 (2) |
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τ2mS14-Y2Al3Si2 | 29.0, 44.0, 27.0 | 1.0112 (8) | 0.4019 (3) | 0.6564 (7) | 100.98 | ||
HoSi2−aoI12-GdSi2 | 36.0, 0.0, 64.0 | 0.3929 (4) | 0.4019 (2) | 1.3348 (8) |
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18 | 4.0, 60.5, 35.5 | Si cF8-Cdiam | 0.0, 0.0, 100.0 | 0.5427 (2) |
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Al cF4-Cu | 0.0, 100.0, 0.0 | 0.4046 (1) |
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τ2mS14-Y2Al3Si2 | 29.5, 44.0, 26.5 | 1.0083 (5) | 0.4013 (2) | 0.6560 (4) | 100.81 |